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Merck
CN

19978

tert-Butylhydrazine hydrochloride

purum, ≥97.0% (AT)

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About This Item

Linear Formula:
(CH3)3CNHNH2 · HCl
CAS Number:
Molecular Weight:
124.61
EC Number:
231-001-6
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
3651224
MDL number:
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grade

purum

assay

≥97.0% (AT)

mp

191-194 °C (lit.)

solubility

H2O: soluble 1 g/10 mL, clear, colorless

SMILES string

Cl.CC(C)(C)NN

InChI

1S/C4H12N2.ClH/c1-4(2,3)6-5;/h6H,5H2,1-3H3;1H

InChI key

DDPWVABNMBRBFI-UHFFFAOYSA-N

Application

tert-Butylhydrazine hydrochloride was used in the synthesis of diphosphinohydrazines R-NH-N(PPh2)2 (where R = tBu).

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Information

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Alexander N Kornev et al.
Inorganic chemistry, 51(2), 874-881 (2012-01-03)
Reactions of diphosphinohydrazines R-NH-N(PPh(2))(2) (R = tBu (1), Ph(2)P (3)) with some metalation reagents (Co[N(SiMe(3))(2)](2), LiN(SiMe(3))(2), La[N(SiMe(3))(2)](3), nBuLi, MeLi) were performed. Compound 1 was synthesized by the reaction of Ph(2)PCl with tert-butylhydrazine hydrochloride in 83% yield. This compound reveals temperature-dependent

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