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About This Item
Linear Formula:
(C6H5)3P(Br)CH2CH2CH2CH3
CAS Number:
Molecular Weight:
399.30
EC Number:
217-219-4
UNSPSC Code:
12352000
MDL number:
Beilstein/REAXYS Number:
3580224
grade
purum
assay
≥98.0% (AT)
mp
240-242 °C, 240-243 °C (lit.)
SMILES string
[Br-].CCCC[P+](c1ccccc1)(c2ccccc2)c3ccccc3
InChI
1S/C22H24P.BrH/c1-2-3-19-23(20-13-7-4-8-14-20,21-15-9-5-10-16-21)22-17-11-6-12-18-22;/h4-18H,2-3,19H2,1H3;1H/q+1;/p-1
InChI key
IKWKJIWDLVYZIY-UHFFFAOYSA-M
Application
Reactant for:
- Free radical 5-exo-dig cyclization
- Intramolecular hydroacylalkoxylation
- Wittig reactions for stereoselective synthesis of alkenes
- Dimerization of α-olefins
- Alkylidenation of hydrazides for synthesis of indoles
- Tandem cyclization and 1,2-thiolate shift of nitrogen ylides
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