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Merck
CN

21287

(1S)-(−)-Camphanic chloride

derivatization grade (chiral), LiChropur™, ≥98.0%

Synonym(s):

(−)-Camphanoyl chloride, (1S)-3-Oxo-4,7,7-trimethyl-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride

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About This Item

Linear Formula:
C10H13O3Cl
CAS Number:
39637-74-6
Molecular Weight:
216.66
UNSPSC Code:
23151817
NACRES:
NA.22
PubChem Substance ID:
329752132
EC Number:
254-552-4
Beilstein/REAXYS Number:
3590860
MDL number:
MFCD00135626
Assay:
≥98.0% (AT)
≥98.0%
Form:
solid

Key Documents

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Product Name

(1S)-(−)-Camphanic chloride, derivatization grade (chiral), LiChropur™, ≥98.0%

InChI key

PAXWODJTHKJQDZ-VHSXEESVSA-N

InChI

1S/C10H13ClO3/c1-8(2)9(3)4-5-10(8,6(11)12)14-7(9)13/h4-5H2,1-3H3/t9-,10+/m0/s1

SMILES string

CC1(C)[C@@]2(C)CC[C@@]1(OC2=O)C(Cl)=O

grade

derivatization grade (chiral)

product line

ChiraSelect™

assay

≥98.0% (AT)
≥98.0%

form

solid

optical activity

[α]20/D −18±1°, c = 2% in carbon tetrachloride

optical purity

enantiomeric ratio: ≥99.5:0.5 (GC)

quality

LiChropur™

technique(s)

HPLC: suitable

mp

67-70 °C
71-73 °C (lit.)

storage temp.

−20°C

Quality Level

100

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Application

(1S)-(-)-Camphanic chloride may be used in esterification of enantiomers in volatiles releasedf from wheat, in order to determine the proportion of enantiomers and also in quantifying the esters.

General description

(1S)-(-)-Camphanic chloride is a derivatizing agent.

Other Notes

Chiral derivatizing reagent used for the determination of enantiomeric purity of alcohols and amines by HPLC
Discover LiChropur reagents ideal for HPLC or LC-MS analysis

Legal Information

ChiraSelect is a trademark of Sigma-Aldrich Co. LLC
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
BCCB0598

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K.D. Ward et al.
Journal of Chromatography A, 478, 169-169 (1989)
Activity of enantiomers of sulcatol on apterae of Rhopalosiphum padi.
Quiroz, A., and H. M. Niemeyer.
Journal of Chemical Ecology, 24, 361-370 (1998)
H. Gerlach
Helvetica Chimica Acta, 68, 1815-1815 (1985)
A. Haag et al.
Helvetica Chimica Acta, 63, 10-10 (1980)
J.D. Fourneron et al
The Journal of Organic Chemistry, 54, 4686-4686 (1989)
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