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Merck
CN

21382

(1R)-(−)-10-Camphorsulfonyl chloride

97.0-103.0% (AT)

Synonym(s):

(−)-Camphor-10-sulfonyl chloride, (1R)-Camphor-10-sulfonic acid chloride

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About This Item

Empirical Formula (Hill Notation):
C10H15ClO3S
CAS Number:
39262-22-1
Molecular Weight:
250.74
PubChem Substance ID:
329752151
UNSPSC Code:
23151817
Beilstein/REAXYS Number:
3205975
MDL number:
MFCD00064155

Key Documents

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SMILES string

[H][C@]12CC[C@](CS(Cl)(=O)=O)(C(=O)C1)C2(C)C

InChI

1S/C10H15ClO3S/c1-9(2)7-3-4-10(9,8(12)5-7)6-15(11,13)14/h7H,3-6H2,1-2H3/t7-,10-/m0/s1

InChI key

BGABKEVTHIJBIW-XVKPBYJWSA-N

grade

derivatization grade ((chiral))

assay

97.0-103.0% (AT)

optical activity

[α]20/D −32±2°, c = 1% in chloroform

storage temp.

2-8°C

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

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T Jira et al.
Die Pharmazie, 48(11), 829-833 (1993-11-01)
Investigations on direct separation by RP-HPLC of selected enantiomeric beta-adrenergic active agents are described. R- and S-1-phenylethylisocyanate (PEIC) as well as (1S)-(+)-campher-10-sulfonylchloride (CSC) are used for the derivatization of the compounds. Correlations between chromatographic data and various influences (pH, temperature

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