Skip to Content
Merck
CN

21623

Supelco

Antimony(III) chloride reagent (free of CHC)

for TLC derivatization, SbCl3 29-31 %

Synonym(s):

Carr-Price Reagent (free of CHC)

Sign Into View Organizational & Contract Pricing

Select a Size


About This Item

UNSPSC Code:
23151817
NACRES:
NA.22
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

Quality Level

composition

SbCl3, 29-31%

technique(s)

thin layer chromatography (TLC): suitable

density

1.353-1.365 g/mL at 20 °C

suitability

corresponds to standard for TLC

General description

Antimony(III) chloride is a catalysing agent. The catalytic effect were initially studied in urea, benzaldehyde and methyl isobutyrylacetate to give 6-isopropyl-5-methoxycarbonyl-4-phenyl-3,4-dihydropyrimidin-2(1H)-one.

Application

Antimony(III) chloride may be used as a catalyst in Biginelli reaction of urea, aromatic aldehydes and acetoacetate esters yielding dihydropyrimidinones.

Preparation Note

prepared with Sb2O3 and hydrochloric acid

Signal Word

Danger

Hazard Statements

Hazard Classifications

Aquatic Chronic 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

新产品
This item has

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Antimony (III) chloride-catalysed Biginelli reaction: a versatile method for the synthesis of dihydropyrimidinones through a different reaction mechanism.
Cepanec, Ivica, et al.
Tetrahedron, 63, 11822-11827 (2007)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service