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About This Item
Linear Formula:
ZnBr2
CAS Number:
Molecular Weight:
225.20
EC Number:
231-718-4
UNSPSC Code:
12352300
MDL number:
eCl@ss:
38150410
grade
reagent grade
assay
≥98%
mp
394 °C (lit.)
SMILES string
Br[Zn]Br
InChI
1S/2BrH.Zn/h2*1H;/q;;+2/p-2
InChI key
VNDYJBBGRKZCSX-UHFFFAOYSA-L
Application
Optimal catalyst for stereospecific and regioselective reaction of silacyclopropanes with carbonyl compounds.
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1
Storage Class
8B - Non-combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Regulatory Information
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Selective N-deacylation of N, O-protected nucleosides by zinc bromide.
Kierzek R, et al.
Tetrahedron Letters, 22(38), 3761-3764 (1981)
Zinc bromide promoted allylation of aluminum acetals derived from perfluoro carboxylic acid esters and diisobutylaluminum hydride. New convenient access to a-perfluoroalkylated homoallyl alcohols.
Ishihara T, et al.
Tetrahedron Letters, 34(36), 5777-5777 (1993)
γ-Alkylation of unsaturated ketones and esters: zinc bromide-catalysed alkylation of O-silylated dienolates.
Fleming I, et al.
Tetrahedron Letters, 20(34), 3209-3212 (1979)


