23514
2-Chloro-1,3,2-benzodioxaphosphorin-4-one
purum, ≥95.0% (AT)
Synonym(s):
Salicyl chlorophosphite
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About This Item
Empirical Formula (Hill Notation):
C7H4ClO3P
CAS Number:
Molecular Weight:
202.53
PubChem Substance ID:
UNSPSC Code:
12350000
Beilstein/REAXYS Number:
1311951
MDL number:
grade
purum
assay
≥95.0% (AT)
bp
127-128 °C/11 mmHg (lit.)
mp
36-40 °C (lit.)
storage temp.
2-8°C
SMILES string
ClP1OC(=O)c2ccccc2O1
InChI
1S/C7H4ClO3P/c8-12-10-6-4-2-1-3-5(6)7(9)11-12/h1-4H
InChI key
BVOITXUNGDUXRW-UHFFFAOYSA-N
Other Notes
Phosphitylating agent for nucleosides and carbohydrates; Synthesis of triphosphates and 1-thiotriphosphates from alcohols
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J.P.G. Hermans et al.
Rec. Trav. Chim., 105, 510-510 (1986)
J.E. Marugg et al.
Tetrahedron Letters, 27, 2661-2661 (1986)
Yuka Kato et al.
Nucleic acids research, 33(9), 2942-2951 (2005-05-26)
The synthesis of the triphosphates of 4'-thiouridine and 4'-thiocytidine, 4'-thioUTP (7; thioUTP) and 4'-thioCTP (8; thioCTP), and their utility for SELEX (systematic evolution of ligands by exponential enrichment) is described. The new nucleoside triphosphate (NTP) analogs 7 and 8 were
P. Westerduin et al.
Tetrahedron Letters, 27, 6271-6271 (1986)
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