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25204

Ammonium formate

Name: Ammonium formate
Brand: SIAL

purum, ≥98%

Synonym(s):

Formic acid ammonium salt

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About This Item

Linear Formula:

HCO₂NH₄

CAS Number:

540-69-2

Molecular Weight:

63.06

EC Number:

208-753-9

UNSPSC Code:

12352300

PubChem Substance ID:

329752783

Beilstein/REAXYS Number:

3625095

MDL number:

MFCD00013103

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grade

purum

assay

≥98%

impurities

≤0.002% heavy metals (as Pb)

pH

6-7 (20 °C, 5%)

mp

119-121 °C (lit.)

density

1.26 g/mL at 25 °C (lit.)

anion traces

chloride (Cl^-): ≤50 mg/kg, sulfate (SO₄^2-): ≤100 mg/kg

cation traces

Fe: ≤20 mg/kg

SMILES string

N.OC=O

InChI

1S/CH2O2.H3N/c2-1-3;/h1H,(H,2,3);1H3

InChI key

VZTDIZULWFCMLS-UHFFFAOYSA-N

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Other Notes

A -D suffix exists for administrative purposes only.
All -D packages are 100% the same product, same quality, same specification as the package sizes previously sold without a -D.

pictograms

GHS07

signalword

Warning

hcodes

H319

pcodes

P264 - P280 - P305 + P351 + P338 - P337 + P313

Hazard Classifications

Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Debenzylation of N-benzylamino derivatives by catalytic transfer hydrtyation with ammonium formate.

Ram S and Spicer LD.

Synthetic Communications, 17(4), 415-418 (1987)

General screening and optimization strategy for fast chiral separations in modern supercritical fluid chromatography.

Lucie Nováková et al.

Analytica chimica acta, 950, 199-210 (2016-12-06)

High throughput general chiral screening method using supercritical fluid chromatography was developed. This method takes an advantage of very fast gradient screening (3 min + 1 min isocratic hold) and generic enantioselectivity of the combined additive formed by 0.1% trifluoroacetic (TFA) acid and 0.1%

Rapid debenzylation of N-benzylamino derivatives to amino-derivatives using ammonium formate as catalytic hydrogen transfer agent.

Ram S and Spicer LD.

Tetrahedron Letters, 28(5), 515-516 (1987)

A convenient method for the N-formylation of secondary amines and anilines using ammonium formate.

Reddy PG, et al.

Tetrahedron Letters, 41(47), 9149-9151 (2000)

The palladium assisted transfer reduction of a, ?-unsaturated nitroalkenes to oximes using ammonium formate.

Kabalka GW, et al.

Synthetic Communications, 20(16), 2453-2458 (1990)

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