25300
(Chloromethyl)trimethylsilane
purum, ≥98.0% (GC)
Synonym(s):
(Trimethylsilyl)methyl chloride
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About This Item
Linear Formula:
(CH3)3SiCH2Cl
CAS Number:
Molecular Weight:
122.67
EC Number:
219-058-5
UNSPSC Code:
12352103
PubChem Substance ID:
Beilstein/REAXYS Number:
906705
MDL number:
vapor pressure
~25 mmHg ( 20 °C)
grade
purum
assay
≥98.0% (GC)
refractive index
n20/D 1.418 (lit.)
bp
98-99 °C (lit.)
density
0.879 g/mL at 25 °C (lit.)
SMILES string
C[Si](C)(C)CCl
InChI
1S/C4H11ClSi/c1-6(2,3)4-5/h4H2,1-3H3
InChI key
OOCUOKHIVGWCTJ-UHFFFAOYSA-N
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Other Notes
Reagent for the Peterson olefination and the homologation of ketones and aldehydes via α,β-epoxysilanes, reviews ; For the synthesis of allylsilanes
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T.V. Lee et al.
Tetrahedron, 45, 5877-5877 (1989)
E.W. Colvin
Silicon Reagents for Organic Synthesis (1988)
M.B. Anderson et al.
Synthetic Communications, 17, 621-621 (1987)
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