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Merck
CN

270636

Chloroform

suitable for HPLC, ≥99.8%

Synonym(s):

Methylidyne trichloride, Trichloromethane

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About This Item

Empirical Formula (Hill Notation):
CHCl3
CAS Number:
Molecular Weight:
119.38
EC Number:
200-663-8
UNSPSC Code:
12190000
PubChem Substance ID:
Beilstein/REAXYS Number:
1731042
MDL number:
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InChI key

HEDRZPFGACZZDS-UHFFFAOYSA-N

InChI

1S/CHCl3/c2-1(3)4/h1H

SMILES string

ClC(Cl)Cl

vapor density

4.1 (vs air)

vapor pressure

160 mmHg ( 20 °C)

assay

≥99.8%

form

liquid

purified by

glass distillation

contains

amylenes as stabilizer

technique(s)

HPLC: suitable

impurities

Acetone and aldehyde, passes test, Acid and chloride, passes test, Free chlorine (Cl), passes test, H2SO4, passes test (darkened), <0.010% water

evapn. residue

<0.0003%

color

APHA: ≤10

Quality Level

mp

−63 °C (lit.)

cation traces

Pb: ≤0.05 ppm

λ

H2O reference

UV absorption

λ: 245 nm Amax: 1.00, λ: 255 nm Amax: 0.150, λ: 260 nm Amax: 0.150, λ: 270 nm Amax: 0.020, λ: 290-400 nm Amax: 0.010

suitability

passes test for HPLC, passes test for dithizone test

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pictograms

Skull and crossbonesHealth hazard

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Oral - STOT SE 3

target_organs

Liver,Kidney, Respiratory system

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 3

flash_point_f

does not flash

flash_point_c

does not flash

ppe

Eyeshields, Faceshields, Gloves

Regulatory Information

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Lipase-catalyzed ring-opening polymerization of trimethylene carbonate.
Bisht KS, et al.
Macromolecules, 30(25), 7735-7742 (1997)
Kristof E Maudens et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 848(2), 384-390 (2006-11-23)
Chloroform is commonly used to extract anthracyclines from various biological matrices. However, their determination can be seriously compromised by phosgene traces present as a result of failing stabilization of chloroform. Out of the three varieties in which chloroform exists (not
High activity and regenerability of a palladium-gold catalyst for chloroform degradation.
Velazquez JC, et al.
Journal of Chemical Technology and Biotechnology (2015)
Yongjun Liu et al.
Journal of hazardous materials, 308, 84-90 (2016-01-26)
In this study, efficient dechlorination and decomposition of chloroform (CF) induced by glow discharge plasma (GDP) in contact with a sodium sulfate solution was investigated. Intermediate byproducts were determined by ionic chromatography and headspace gas chromatography, respectively. Results showed that
Photolysis of chloroform and other organic molecules in aqueous titanium dioxide suspensions.
Kormann C, et al.
Environmental Science & Technology, 25(3), 494-500 (1991)

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