28995
cis-1,2-Cyclohexanediol
puriss., ≥99.0% (GC)
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About This Item
Linear Formula:
C6H10(OH)2
CAS Number:
Molecular Weight:
116.16
PubChem Substance ID:
UNSPSC Code:
12352100
Beilstein/REAXYS Number:
1340578
MDL number:
grade
puriss.
assay
≥99.0% (GC)
mp
97-101 °C
SMILES string
O[C@@H]1CCCC[C@@H]1O
InChI
1S/C6H12O2/c7-5-3-1-2-4-6(5)8/h5-8H,1-4H2/t5-,6+
InChI key
PFURGBBHAOXLIO-OLQVQODUSA-N
Other Notes
Starting material for several enantioselective enzymatic transformations, e.g. mono-acylation; mono-oxidation
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P. Adlercreutz
Applied Microbiology and Biotechnology, 30, 257-257 (1989)
H.-J. Gais et al.
Tetrahedron Letters, 29, 5743-5743 (1988)
J Mráz et al.
Scandinavian journal of work, environment & health, 25(3), 233-237 (1999-08-18)
This study explored the acute effect of ethanol (EtOH) on the urinary excretion of cyclohexanol (CH-ol), 1,2- and 1,4-cyclohexanediol (CH-diol), biomarkers of exposure to important solvents, and chemical intermediates cyclohexanone (CH-one), cyclohexane (CH) and cyclohexanol. Volunteers (5-8 in each group)
M Tanaka et al.
The Journal of organic chemistry, 66(8), 2667-2673 (2001-04-17)
Diastereoselective alkylation of ethyl 2-methyl- and/or 2-ethylacetoacetates using the (S,S)-cyclohexane-1,2-diol as an acetal chiral auxiliary afforded enol ethers (2a-f and 5a-f) of 92->95% de in 31-70% yields. Removal of the cyclohexane-1,2-diol with BF(3)-OEt(2) afforded beta-keto esters (3 and 6) bearing
Yoshihito Shiota et al.
Inorganic chemistry, 50(13), 6200-6209 (2011-06-04)
The catalytic conversion of 1,2-cyclohexanediol to adipic anhydride by Ru(IV)O(tpa) (tpa ═ tris(2-pyridylmethyl)amine) is discussed using density functional theory calculations. The whole reaction is divided into three steps: (1) formation of α-hydroxy cyclohexanone by dehydrogenation of cyclohexanediol, (2) formation of
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