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Merck
CN

293733

Benzophenone imine

95%

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About This Item

Linear Formula:
(C6H5)2C=NH
CAS Number:
1013-88-3
Molecular Weight:
181.23
UNSPSC Code:
12171500
NACRES:
NA.47
PubChem Substance ID:
24857673
MDL number:
MFCD00001760
Beilstein/REAXYS Number:
1100371

Key Documents

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Product Name

Benzophenone imine, 95%

InChI

1S/C13H11N/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,14H

SMILES string

N=C(c1ccccc1)c2ccccc2

InChI key

SXZIXHOMFPUIRK-UHFFFAOYSA-N

assay

95%

form

liquid

technique(s)

titration: suitable

refractive index

n20/D 1.618 (lit.)

bp

151-153 °C/10 mmHg (lit.)

density

1.08 g/mL at 25 °C (lit.)

application(s)

diagnostic assay manufacturing
hematology
histology

storage temp.

room temp

Quality Level

100

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Application

Benzophenone imine is useful for the preparation of nitrile yield dimers.

General description

Benzophenone imine plays a vital role as an ammonia surrogate. It is primarily used as ammonia equivalents for the selective formation of protected primary amines. Benzophenone imine is useful as a synthetic intermediate, especially for the synthesis of glycine Schiff base.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

228.2 °F - closed cup

flash_point_c

109 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
STBH3217
STBH3025
STBG8571
STBG8254
STBF4865V

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Suzanne Fergus et al.
The Journal of organic chemistry, 69(14), 4663-4669 (2004-07-03)
A series of novel hexaaryl diazatrienes 5 ("nitrile ylide dimers") were synthesized directly from the corresponding diaryl ketimines 12 and dichlorotoluenes 13 in a facile one-pot synthesis. The carbene character of the nitrile ylides was investigated by varying the substituents
Lukas Lohmeyer et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 26(26), 5834-5845 (2020-02-06)
New redox-active 1,2,5,6-tetrakis(guanidino)-naphthalene compounds, isolable and storable in the neutral and deep-green dicationic redox states and oxidisable further in two one-electron steps to the tetracations, are reported. Protonation switches on blue fluorescence, with the fluorescence intensity (quantum yield) increasing with

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