29819
Methyl 1-cyclopentene-1-carboxylate
purum, ≥95.0% (GC)
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About This Item
Linear Formula:
C5H7CO2CH3
CAS Number:
Molecular Weight:
126.15
UNSPSC Code:
12352100
Beilstein/REAXYS Number:
2040162
MDL number:
grade
purum
assay
≥95.0% (GC)
refractive index
n20/D 1.4660 (lit.), n20/D 1.467
bp
76-78 °C/9 mmHg (lit.)
density
1.031 g/mL at 20 °C (lit.)
SMILES string
COC(=O)C1=CCCC1
InChI
1S/C7H10O2/c1-9-7(8)6-4-2-3-5-6/h4H,2-3,5H2,1H3
InChI key
VTYCAXIAUKEGBQ-UHFFFAOYSA-N
General description
Asymmetric oxidative Heck reaction of methyl 1-cyclopentene-1-carboxylate and phenyl boronic acid using Pd-ligand complexes has been reported.
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Kyung Soo Yoo et al.
The Journal of organic chemistry, 75(1), 95-101 (2009-12-04)
Chiral dimeric tridentate NHC-amidate-alkoxide palladium(II) complexes, 3a and 3b, effected oxidative boron Heck-type reactions of aryl boronic acids with both acyclic and cyclic alkenes at room temperature to afford the corresponding coupling products with high enantioselectivities. The high degree of
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