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Merck
CN

31413

Magnesium chloride hexahydrate

puriss. p.a., ACS reagent, reag. ISO, ≥99%

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About This Item

Linear Formula:
MgCl2 · 6H2O
CAS Number:
Molecular Weight:
203.30
UNSPSC Code:
12352300
PubChem Substance ID:
EC Number:
232-094-6
MDL number:
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InChI key

DHRRIBDTHFBPNG-UHFFFAOYSA-L

InChI

1S/2ClH.Mg.6H2O/h2*1H;;6*1H2/q;;+2;;;;;;/p-2

SMILES string

O.O.O.O.O.O.Cl[Mg]Cl

grade

ACS reagent, puriss. p.a.

agency

reag. ISO

assay

≥99%

impurities

≤0.0005% heavy metals (as Pb), ≤0.001% ammonium (NH4), ≤0.005% in water insoluble matters

pH

5-6.5 (20 °C, 5%)

anion traces

nitrate (NO3-): ≤10 mg/kg, phosphate (PO43-): ≤5 mg/kg, sulfate (SO42-): ≤20 mg/kg

cation traces

Ba: ≤20 mg/kg, Ca: ≤100 mg/kg, Cu: ≤5 mg/kg, Fe: ≤5 mg/kg, K: ≤10 mg/kg, Mn: ≤5 mg/kg, Na: ≤10 mg/kg, Sr: ≤20 mg/kg, Zn: ≤10 mg/kg

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General description

Magnesium chloride hexahydrate is a colorless, crystalline solid. On heating, it loses water of crystallization and affords magnesium oxide. It is a promising phase change material (PCM). Due to its suitable thermo-physical properties, it can be used as storage media in solar cookers. Its flame retardancy action on 100% woven cotton fabric has been investigated. Its heat capacity has been evaluated.

Application

Magnesium chloride hexahydrate may be employed as a catalyst for the synthesis of 3,4-dihydropyrimidin-2-(1H)-one by Biginelli condensation reaction.

Other Notes

A -D suffix exists for administrative purposes only.
All -D packages are 100% the same product, same quality, same specification as the package sizes previously sold without a -D.

Storage Class

13 - Non Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Information

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One thousand thermal cycles of magnesium chloride hexahydrate as a promising PCM for indoor solar cooking.
El-Sebaii AA, et al.
Energy Conversion and Management , 52(4), 1771-1777 (2011)
Study of magnesium chloride hexahydrate as heat storage material.
Pilar R, et al.
Thermochimica Acta, 546, 81-86 (2012)
Magnesium Chloride Hexahydrate Catalyzed One-Pot Synthesis of 3, 4-Dihydropyrimidin-2-(1 H) ones Under Solvent-Free Conditions.
Zhang GL and Cai XH.
Synthetic Communications, 35(6), 829-833 (2005)
Thermal decomposition pathway of a cellulosic fabric impregnated by magnesium chloride hexahydrate as a flame-retardant.
Mostashari SM and Moafi HF.
Journal of Thermal Analysis and Calorimetry, 93(2), 589-594 (2008)
Monica Mazzarino et al.
Analytica chimica acta, 837, 70-82 (2014-07-09)
This article describes a liquid chromatographic/tandem mass spectrometric method, based on the use of precursor ion scan as the acquisition mode, specifically developed to detect indole-derived cannabinoids (phenylacetylindoles, naphthoylindoles and benzoylindoles) in biological fluids (saliva, urine and blood). The method

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