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Merck
CN

31490

Sigma-Aldrich

(Diacetoxyiodo)benzene

purum, ≥98.0% (AT)

Synonym(s):

Iodobenzene I,I-diacetate, Iodosobenzene I,I-diacetate

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About This Item

Linear Formula:
C6H5I(O2CCH3)2
CAS Number:
Molecular Weight:
322.10
Beilstein:
1879369
EC Number:
MDL number:
UNSPSC Code:
12352000
PubChem Substance ID:
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grade

purum

Assay

≥98.0% (AT)

reaction suitability

reagent type: oxidant

mp

161-163 °C (lit.)
161-163 °C

SMILES string

CC(OI(OC(C)=O)C1=CC=CC=C1)=O

InChI

1S/C10H11IO4/c1-8(12)14-11(15-9(2)13)10-6-4-3-5-7-10/h3-7H,1-2H3

InChI key

ZBIKORITPGTTGI-UHFFFAOYSA-N

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Other Notes

Reagent for the cleavage of vic-glycols, hydroxylations and many other oxidation reactions, review; Preparation of the thermally unstable iodosobenzene

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H. Saltzman et al.
Organic Syntheses, 5 (Coll), 658-658 (1973)
A. Varvoglis
Synthesis, 709-709 (1984)

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