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Pyrimethanil

PESTANAL®, analytical standard

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Synonym(s):
2-Anilino-4,6-dimethylpyrimidine
Empirical Formula (Hill Notation):
C12H13N3
CAS Number:
53112-28-0
Molecular Weight:
199.25
Beilstein:
151589
EC Number:
414-220-3
MDL number:
MFCD00172113
PubChem Substance ID:
329753829
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

Cc1cc(C)nc(Nc2ccccc2)n1

InChI

1S/C12H13N3/c1-9-8-10(2)14-12(13-9)15-11-6-4-3-5-7-11/h3-8H,1-2H3,(H,13,14,15)

InChI key

ZLIBICFPKPWGIZ-UHFFFAOYSA-N

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General description

Pyrimethanil is an anilino-pyrimidine, broad spectrum fungicide primarily used for the control of gray mould and leaf scab on fruits, vegetables and ornamentals. Its mode of action involves inhibition of the secretion of hydrolytic enzymes by the fungi during the infection process, thus stopping the further development of the disease.

Application

Pyrimethanil may be used as a reference standard for the determination of the analyte in fruits and ketchup samples by gas chromatography-mass spectrometry in combination with headspace solid-phase microextraction method.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Environment
GHS09

Hazard Statements

H411

Precautionary Statements

P273

Hazard Classifications

Aquatic Chronic 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

农药列管产品

Certificates of Analysis (COA)

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T1503
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25G
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705578-5MG-PW

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1000309185

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Determination of pyrimethanil and kresoxim-methyl in green groceries by headspace solid-phase microextraction and gas chromatography-mass spectrometry.
Navalon A, et al.
Journal of Chromatography A, 975(2), 355-360 (2002)
Xiangyang Yu et al.
Journal of environmental sciences (China), 22(4), 615-620 (2010-07-14)
Biochar derived from partial combustion of vegetation is ubiquitous and potentially effective in sequestration of environmental contaminants. Biochars were prepared by burning of red gum (Eucalyptus spp.) woodchips at 450 and 850 degrees C (labeled as BC450 and BC850). These
Rapid and sensitive detection of pyrimethanil residues on pome fruits by Surface Enhanced Raman Scattering.
Mandrile L, et al.
Food Chemistry, 244, 16-24 (2018)
Luisa Mandrile et al.
Biosensors, 9(4) (2019-12-22)
Flexible and transparent substrates are emerging as low cost and easy-to-operate support for surface-enhanced Raman spectroscopy (SERS). In particular, in situ SERS detection approach for surface characterization in transmission modality can be efficiently employed for non-invasive analysis of non-planar surfaces.
Carla Sirtori et al.
Journal of hazardous materials, 217-218, 217-223 (2012-03-31)
This study evaluated the formation of chlorinated transformation products during photo-Fenton treatment of pyrimethanil (PYR-20 mg L(-1)) in two water matrices, demineralised water (DW) and water containing 5 g L(-1) of NaCl (DW(NaCl)). All experiments were carried out in compound
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