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Merck
CN

31587

(+)-O,O′-Diacetyl-L-tartaric anhydride

purum, ≥97.0% (NT)

Synonym(s):

(+)-Diacetyl-L-tartaric anhydride

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About This Item

Empirical Formula (Hill Notation):
C8H8O7
CAS Number:
Molecular Weight:
216.14
EC Number:
228-502-7
UNSPSC Code:
12352005
PubChem Substance ID:
Beilstein/REAXYS Number:
87315
MDL number:
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grade

purum

assay

≥97.0% (NT)

optical activity

[α]20/D +60±2°, c = 6% in acetone

mp

130-135 °C

storage temp.

−20°C

SMILES string

CC(=O)O[C@@H]1[C@@H](OC(C)=O)C(=O)OC1=O

InChI

1S/C8H8O7/c1-3(9)13-5-6(14-4(2)10)8(12)15-7(5)11/h5-6H,1-2H3/t5-,6-/m1/s1

InChI key

XAKITKDHDMPGPW-PHDIDXHHSA-N

Other Notes

Reagent for the chiral derivatization of amino alcohols; Preparation of tartramide chiral stationary phase for HPLC; Partial kinetic resolution of alcohols


Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Y. Dobashi et al.
The Journal of Organic Chemistry, 52, 2490-2490 (1987)
K.H. Bell
Australian Journal of Chemistry, 34, 671-671 (1981)
W. Lindner et al.
Journal of Chromatography A, 316, 605-605 (1984)