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Merck
CN

32433

Supelco

Primisulfuron-methyl

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C15H12F4N4O7S
CAS Number:
86209-51-0
Molecular Weight:
468.34
Beilstein:
6673850
MDL number:
MFCD00337169
UNSPSC Code:
41116107
PubChem Substance ID:
329754209
NACRES:
NA.24

Key Documents

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grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

COC(=O)c1ccccc1S(=O)(=O)NC(=O)Nc2nc(OC(F)F)cc(OC(F)F)n2

InChI

1S/C15H12F4N4O7S/c1-28-11(24)7-4-2-3-5-8(7)31(26,27)23-15(25)22-14-20-9(29-12(16)17)6-10(21-14)30-13(18)19/h2-6,12-13H,1H3,(H2,20,21,22,23,25)

InChI key

ZTYVMAQSHCZXLF-UHFFFAOYSA-N

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General description

Primisulfuron-methyl belongs to the class of sulfonylurea herbicides.

Application

Primisulfuron-methyl may be used as an analytical reference standard for the determination of the analyte in:
  • Surface and groundwater samples by solid-phase extraction (SPE) and high performance liquid chromatography-electrospray ionization-mass spectrometry (HPLC/ESI-MS).
  • Tap and leaching water samples by SPE and LC coupled to tandem mass spectrometry (MS/MS) with ESI and selected reaction monitoring (SRM) detection.
  • Wine samples by vortex-assisted ionic liquid dispersive liquid–liquid microextraction ((VA-IL-DLLME)) and capillary HPLC.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Environment
GHS09

Signal Word

Warning

Hazard Statements

H400

Precautionary Statements

P273 - P391 - P501

Hazard Classifications

Aquatic Acute 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
BCCJ3729
BCBW9630

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Vortex-assisted ionic liquid dispersive liquid-liquid microextraction for the determination of sulfonylurea herbicides in wine samples by capillary high-performance liquid chromatography.
Gure A, et al.
Food Chemistry, 170(2-3), 348-353 (2015)
Olivier Cagnac et al.
Plant physiology, 135(3), 1378-1387 (2004-07-13)
The oligopeptide transporter (OPT) family contains nine members in Arabidopsis. While there is some evidence that AtOPTs mediate the uptake of tetra- and pentapeptides, OPT homologs in rice (Oryza sativa; OsGT1) and Indian mustard (Brassica juncea; BjGT1) have been described
Development and validation of a solid-phase extraction method coupled to high-performance liquid chromatography with ultraviolet-diode array detection for the determination of sulfonylurea herbicide residues in bovine milk samples.
Seccia S, et al.
Journal of Chromatography A, 1218(9), 1253-1259 (2011)
I Braschi et al.
Journal of agricultural and food chemistry, 48(6), 2565-2571 (2000-07-11)
Microbial degradation of the herbicide primisulfuron was investigated using enrichment cultures from contaminated soils and 20 axenic cultures. At neutral pH, no disappearance of the herbicide was detected either in the enrichment cultures or in the growth media of the
Trace analysis of sulfonylurea herbicides in water samples by solid-phase extraction and liquid chromatography-tandem mass spectrometry.
Fenoll J, et al.
Talanta, 101(2-3), 273-282 (2012)
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