32445
Diethylphenylphosphine
purum, ≥97.0% (GC)
Synonym(s):
NSC 158475
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About This Item
Linear Formula:
(C2H5)2PC6H5
CAS Number:
Molecular Weight:
166.20
EC Number:
216-516-6
UNSPSC Code:
12352002
PubChem Substance ID:
Beilstein/REAXYS Number:
742484
MDL number:
InChI key
LVTCZSBUROAWTE-UHFFFAOYSA-N
InChI
1S/C10H15P/c1-3-11(4-2)10-8-6-5-7-9-10/h5-9H,3-4H2,1-2H3
SMILES string
CCP(CC)c1ccccc1
grade
purum
assay
≥97.0% (GC)
refractive index
n20/D 1.546 (lit.)
bp
120-121 °C/29 mmHg (lit.)
density
0.954 g/mL at 25 °C (lit.)
Application
Catalyst for:
- Selective cross-dimerization
- Diastereoselective condensations
- Carboxyl migration reactions
- Selective hydrogenation
- Asymmetric induction by chiral diphosphines in ring contraction
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B P Smyser et al.
Biochemical pharmacology, 35(10), 1719-1723 (1986-05-15)
Purified mouse liver cytochrome P-450 reconstituted with purified NADPH-cytochrome P-450 reductase and phosphatidylcholine metabolized diethylphenylphosphine to diethylphenylphosphine oxide. NADPH was required for the reaction and the amount of oxide formed was time and cytochrome P-450 dependent. Purified phenobarbital-induced cytochrome P-450
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