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Merck
CN

32606

Fumonisin B3 solution

~50 μg/mL in acetonitrile: water, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C34H59NO14
CAS Number:
Molecular Weight:
705.83
UNSPSC Code:
85151701
NACRES:
NA.24
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
8181181
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InChI key

CPCRJSQNWHCGOP-ZBUYIUKQSA-N

SMILES string

CCCC[C@@H](C)[C@@H](OC(=O)CC(CC(O)=O)C(O)=O)[C@H](C[C@@H](C)C[C@H](O)CCCCCC[C@H](O)[C@@H](C)N)OC(=O)CC(CC(O)=O)C(O)=O

InChI

1S/C34H59NO14/c1-5-6-11-21(3)32(49-31(43)19-24(34(46)47)17-29(40)41)27(48-30(42)18-23(33(44)45)16-28(38)39)15-20(2)14-25(36)12-9-7-8-10-13-26(37)22(4)35/h20-27,32,36-37H,5-19,35H2,1-4H3,(H,38,39)(H,40,41)(H,44,45)(H,46,47)/t20-,21+,22+,23?,24?,25+,26-,27-,32+/m0/s1

grade

analytical standard

shelf life

limited shelf life, expiry date on the label

concentration

~50 μg/mL in acetonitrile: water

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

solubility

water: soluble

application(s)

cleaning products
cosmetics
food and beverages
personal care

format

single component solution

storage temp.

−20°C

Quality Level

General description

Certan Vial
Fumonisins are mycotoxins, produced by molds of genus Fusarium. Six types of fumonisins and their structures have been discovered: fumonisin (B1, B2, B3, B4, A1 and A2). Fumonisins are responsible for toxic properties of corn contaminated with Fusarium moniliforme. Simultaneous determination of fumonisin B1, fumonisin B2 and fumonisin B3 in traditional chinese medicines by ultra-high-performance liquid chromatography-tandem mass spectrometry is reported.

Application

Fumonisin B3 may be used as a reference standard for the determination of the analyte in food supplements using liquid chromatography coupled with tandem mass spectrometry (LC-MS/MS).
Fumonisin B3 solution was used as analytical standard in determination of fumonisins in stored wheat samples by HPLC analysis. It may be used as analytical standard in determination of fumonisins B1, B2, and B3 and hydrolyzed fumonisin B1 in corn containing foods.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Analysis Note

purity : ≥95.0% (HPLC)

pictograms

FlameExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2

Storage Class

3 - Flammable liquids

wgk

WGK 2

flash_point_f

42.8 °F - not determined

flash_point_c

6 °C - not determined

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

高风险级别生物产品--病毒,疫苗等
危险化学品
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Paul C Howard et al.
Toxicology and applied pharmacology, 185(3), 153-165 (2002-12-25)
Fumonisinmycotoxins are produced by Fusaria fungi that grow worldwide primarily on corn. Fumonisin B(1), the most predominant form in corn samples, is a renal carcinogen in male F344/N rats and a hepatocarcinogen in female B6C3F(1) mice when fed at concentrations
Chenglan Liu et al.
Mycopathologia, 164(3), 127-134 (2007-07-17)
The present work deals with the capability for producing fumonisin by Fusarium proliferatum strains isolated from asparagus in China. Fifty of F. proliferatum strains were randomly selected and incubated on cultures of maize grain and asparagus spear, respectively. Fumonisin levels
LC-MS/MS multi-analyte method for mycotoxin determination in food supplements.
Mavungu DDJ, et al.
Food Additives and Contaminants, 26(6), 885-895 (2009)
L E Broggi et al.
Food additives and contaminants, 19(5), 465-469 (2002-05-25)
Corn samples and different dry-milled fractions collected from an industrial mill in Argentina were analysed. Average contaminations were FB(1) 1540 microg kg(-1), FB(2) 716 microg kg(-1) and FB(3) 152 microg kg(-1) in whole corn; FB(1) 135 microg kg(-1), FB(2) 39.1
Detection of fumonisins B1, B2, and B3 and hydrolyzed fumonisin B1 in corn-containing foods.
Hopmans EC and Murphy PA.
Journal of Agricultural and Food Chemistry, 41(10), 1655-1658 (1993)

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