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Merck
CN

32805

Mandipropamid

PESTANAL®, analytical standard

Synonym(s):

2-(4-Chlorophenyl)-N-[3-methoxy-4-(2-propynyloxy)phenethyl]-2-(2-propynyloxy)acetamide

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About This Item

Empirical Formula (Hill Notation):
C23H22ClNO4
CAS Number:
Molecular Weight:
411.88
UNSPSC Code:
41116107
NACRES:
NA.24
MDL number:
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InChI

1S/C23H22ClNO4/c1-4-14-28-20-11-6-17(16-21(20)27-3)12-13-25-23(26)22(29-15-5-2)18-7-9-19(24)10-8-18/h1-2,6-11,16,22H,12-15H2,3H3,(H,25,26)

SMILES string

ClC1=CC=C(C(OCC#C)C(NCCC2=CC=C(OCC#C)C(OC)=C2)=O)C=C1

InChI key

KWLVWJPJKJMCSH-UHFFFAOYSA-N

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

Quality Level

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General description

Mandipropamid is a carboxylic acid amide, which belongs to the oomycete class of fungicides. It is found to be effective in controlling phytopathogens such as Plasmopara viticola on grapes and potato late blight caused by Phytophthora infestans.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Environment

signalword

Warning

hcodes

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Information

农药列管产品
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Multicomponent reactions in fungicide research: The discovery of mandipropamid.
Lamberth C, et al.
Bioorganic & Medicinal Chemistry, 16(3), 1531-1545 (2008)
Guofeng Xu et al.
Environmental science and pollution research international, 27(32), 40148-40155 (2020-07-15)
Enantioselective monitoring of chiral fungicide mandipropamid enantiomers were carried out in grapes and wine-making process. The enantiomers of mandipropamid were separated on a Lux Cellulose-2 column and determined by ultra-high-performance liquid chromatography coupled with tandem mass spectrometry (UHPLC-MS/MS). The processing
Mandipropamid targets the cellulose synthase?like PiCesA3 to inhibit cell wall biosynthesis in the oomycete plant pathogen, Phytophthora infestans.
Blum M, et al.
Molecular Plant Pathology, 11(2), 227-243 (2010)
Zhiwen Wang et al.
Pest management science, 76(7), 2525-2536 (2020-02-23)
Phytophthora capsici is a destructive plant oomycete pathogen that could lead to devastating losses in food production. Fungicide application is the main way to control plant disease caused by P. capsici. SYP-14288, a novel fungicide with a unique mode of
Vasileios Vangalis et al.
Journal of fungi (Basel, Switzerland), 6(4) (2020-12-11)
Woronin bodies are membrane-bound organelles of filamentous ascomycetes that mediate hyphal compartmentalization by plugging septal pores upon hyphal damage. Their major component is the peroxisomal protein Hex1, which has also been implicated in additional cellular processes in fungi. Here, we

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