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Merck
CN

33153

Diphenylcarbazone

for spectrophotometric det. of Cd, Cr, Cu, Fe, Hg, Mo

Synonym(s):

Phenylazoformic acid 2-phenylhydrazide

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About This Item

Linear Formula:
C6H5NHNHCON=NC6H5
CAS Number:
Molecular Weight:
240.26
EC Number:
208-698-0
UNSPSC Code:
12352200
PubChem Substance ID:
Beilstein/REAXYS Number:
959475
MDL number:
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description

for metal titration

quality

for spectrophotometric det. of Cd, Cr, Cu, Fe, Hg, Mo

technique(s)

titration: suitable

impurities

insoluble in ethanol, in accordance

ign. residue

≤0.1% (as SO4)

mp

119-123 °C (lit.)

suitability

passes test for Hg detection

SMILES string

O=C(NNc1ccccc1)\N=N\c2ccccc2

InChI

1S/C13H12N4O/c18-13(16-14-11-7-3-1-4-8-11)17-15-12-9-5-2-6-10-12/h1-10,14H,(H,16,18)/b17-15+

InChI key

ZFWAHZCOKGWUIT-BMRADRMJSA-N

Other Notes

Spectrophotometric determination of many metals

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Information

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K.L. Cheng et al. et al.
Handbook of Organic Analytical Reagents null
Z. Anal. Chem., 286, 107-107 (1977)
Katsuhiko Yokoi
Biological trace element research, 85(1), 87-94 (2002-03-08)
A colorimetic method is outlined for the determination of the chloride ion in biological samples (blood serum, plasma, and urine). The present method is based on the quantitative reduction of free mercuric ions by chloride ions. Chloride ions form an
Jing Fan et al.
Journal of hazardous materials, 150(2), 343-350 (2007-06-15)
A new solid-phase extractor, diphenylcarbazone-functionalized silica gel has been synthesized and confirmed by IR and Raman spectrometry. The new solid-phase extractor is found to be stable in 1-6 mol L(-1) HCl or H(2)SO(4), and also in common organic solvents. It
Varinder Kaur et al.
Annali di chimica, 97(3-4), 237-249 (2007-09-08)
Diphenycarbazone has been used for the simultaneous determination of cobalt and nickel by partial least square regression method. DPC complexes of cobalt and nickel at pH 7-10 are of pink color, which are soluble in TX-100 micellar media. A partial

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