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Merck
CN

33325

Potassium phthalate monobasic

puriss. p.a., buffer substance, ≥99.5%

Synonym(s):

KHP, Phthalic acid monopotassium salt, Potassium biphthalate, Potassium hydrogen phthalate

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About This Item

Linear Formula:
HOOCC6H4COOK
CAS Number:
877-24-7
Molecular Weight:
204.22
UNSPSC Code:
12352100
NACRES:
NA.21
PubChem Substance ID:
57648795
EC Number:
212-889-4
Beilstein/REAXYS Number:
3637128
MDL number:
MFCD00013070

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InChI key

IWZKICVEHNUQTL-UHFFFAOYSA-M

InChI

1S/C8H6O4.K/c9-7(10)5-3-1-2-4-6(5)8(11)12;/h1-4H,(H,9,10)(H,11,12);/q;+1/p-1

SMILES string

[K+].OC(=O)c1ccccc1C([O-])=O

grade

puriss. p.a.

assay

≥99.5%

form

solid

loss

≤0.2% loss on drying, 105 °C

pH

4

mp

295-300 °C (dec.) (lit.)

anion traces

chloride (Cl-): ≤10 mg/kg, sulfate (SO42-): ≤50 mg/kg

cation traces

Cd: ≤5 mg/kg, Co: ≤5 mg/kg, Cu: ≤5 mg/kg, Fe: ≤5 mg/kg, Na: ≤100 mg/kg, Ni: ≤5 mg/kg, Pb: ≤5 mg/kg, Zn: ≤5 mg/kg

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General description

Potassium phthalate monobasic is the monopotassium salt of phthalic acid. It has been proposed as a certified reference material (CRM) under ISO/IEC 17025 and ISO Guide 34 accreditation. Its spectral shift, multiplicity, solubility and relaxation times in different solvents have been reported.

Application

Potassium phthalate monobasic may be used as a buffer to maintain pH = 2.39 and 4.52, during the dispersive ionic liquid-liquid microextraction coupled with liquid chromatography and UV detection of drug (benznidazole and nifurtimox) levels in human plasma. It has been used as internal standard certified reference material (CRM) for the high performance (HP)-quantitative NMR spectroscopic (qNMR) determination of various organic compounds.

flash_point_f

387.1 °F - Pensky-Martens closed cup

flash_point_c

197.3 °C - Pensky-Martens closed cup

ppe

Eyeshields, Gloves, type N95 (US)

Storage Class

11 - Combustible Solids

wgk

WGK 1

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
SZBC1240
SZBB0050V
SZBB0050
73020
SZBC1240V

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J M Padró et al.
Talanta, 107, 95-102 (2013-04-20)
Dispersive ionic liquid-liquid microextraction combined with liquid chromatography and UV detection was used for the determination of two antichagasic drugs in human plasma: nifurtimox and benznidazole. The effects of experimental parameters on extraction efficiency-the type and volume of ionic liquid
Martha M Téllez-Rojo et al.
The Science of the total environment, 461-462, 386-390 (2013-06-12)
Previous studies suggest that prenatal phthalate exposure affects neurodevelopment and behavior during the first years of life. To evaluate the effect of maternal urinary concentrations of phthalate metabolites during pregnancy on mental and psychomotor development in children 24-36 months of
Randi J Bertelsen et al.
Environmental health perspectives, 121(2), 251-256 (2012-11-21)
High-molecular-weight phthalates in indoor dust have been associated with asthma in children, but few studies have evaluated phthalate biomarkers in association with respiratory outcomes. We explored the association between urinary concentrations of phthalate metabolites and current asthma. In a cross-sectional
Maria Cristina Fossi et al.
Marine pollution bulletin, 64(11), 2374-2379 (2012-09-12)
Baleen whales are potentially exposed to micro-litter ingestion as a result of their filter-feeding activity. However, the impacts of microplastics on baleen whales are largely unknown. In this case study of the Mediterranean fin whale (Balaenoptera physalus), we explore the
Juanjuan Feng et al.
Journal of chromatography. A, 1268, 16-21 (2012-11-07)
Because of the occurrence of ion exchange between high-ionic-strength solution and anions of polymeric ionic liquids (PILs), PILs based solid-phase microextraction (SPME) fibers were rarely used in direct immersion mode to high-salt-added samples. In this work, a novel double-confined PIL
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