33359
4-Methyl-m-phenylenediamine
standard for GC
Synonym(s):
2,4-Diaminotoluene, 2,4-Toluenediamine, 4-Methyl-1,3-phenylenediamine
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About This Item
Linear Formula:
CH3C6H3(NH2)2
CAS Number:
Molecular Weight:
122.17
EC Number:
202-453-1
UNSPSC Code:
41116107
PubChem Substance ID:
Beilstein/REAXYS Number:
2205839
MDL number:
InChI key
VOZKAJLKRJDJLL-UHFFFAOYSA-N
InChI
1S/C7H10N2/c1-5-2-3-6(8)4-7(5)9/h2-4H,8-9H2,1H3
SMILES string
Cc1ccc(N)cc1N
assay
≥99.0% (GC)
shelf life
limited shelf life, expiry date on the label
technique(s)
HPLC: suitable, gas chromatography (GC): suitable
bp
283-285 °C (lit.)
mp
97-99 °C (lit.), 98-100 °C
application(s)
environmental
Regulatory Information
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Pei-Shan Liu et al.
Toxicology, 219(1-3), 167-174 (2005-12-13)
Toluene diisocyanate (TDI) is widely used as a chemical intermediate in the production of polyurethane. TDI-induced asthma is related to its disturbance of acetylcholine activity in most affected workers, but the relevant mechanisms are unclear. Toluene diamine (TDA) is the
Kazunori Narumi et al.
Mutation research, 747(2), 234-239 (2012-06-09)
Various liver micronucleus assay methods, such as those involving partial hepatectomy, treatment with mitogens, and the use of juvenile animals, have been developed. These assays have been proven to be of high sensitivity and specificity to predict hepatocarcinogenicity of compounds
Isabelle Séverin et al.
Toxicology, 213(1-2), 138-146 (2005-07-06)
2,4-Diaminotoluene (2,4-DAT) is a widely used industrial intermediate and human exposure is possible in the dye and plastics industries. We investigated the genotoxicity of the environmental pollutant, 2,4-DAT, in human HepG2 cells using the unscheduled DNA synthesis (UDS) test, the
Astrid Rohrbeck et al.
Toxicological sciences : an official journal of the Society of Toxicology, 118(1), 31-41 (2010-08-18)
Information on the carcinogenic potential of chemicals is primarily available for High Production Volume (HPV) products. Because of the limited knowledge gain from routine cancer bioassays and the fact that HPV chemicals are tested only, there is the need for
Yi-chu Shan et al.
Se pu = Chinese journal of chromatography, 20(4), 289-294 (2003-01-25)
In high performance liquid chromatography, it is necessary to apply multi-composition gradient elution for the separation of complex samples such as environmental and biological samples. Multivariate stepwise gradient elution is one of the most efficient elution modes, because it combines
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