34150
1,12-Dibromododecane
purum, ≥97.0% (GC)
Synonym(s):
Dodecamethylene dibromide
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About This Item
Linear Formula:
Br(CH2)12Br
CAS Number:
Molecular Weight:
328.13
EC Number:
222-096-5
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
1742763
MDL number:
grade
purum
assay
≥97.0% (GC)
bp
215 °C/15 mmHg (lit.)
mp
38-42 °C
solubility
dioxane: soluble 0.5 g/5mL, clear, colorless
SMILES string
BrCCCCCCCCCCCCBr
InChI
1S/C12H24Br2/c13-11-9-7-5-3-1-2-4-6-8-10-12-14/h1-12H2
InChI key
ZJJATABWMGVVRZ-UHFFFAOYSA-N
General description
1,12-Dibromododecane is an α,ω-dihaloalkane and its crystal structure has been described.
Application
1,12-Dibromododecane was used in synthesis of azobenzene isothiouronium salts of different alkyl chains (dodecyl) via reaction with 4-((4-methylphenyl)azo)phenol. It was also used in preparation of novel tboc-protected ionenes with molecular weight exceeding 30kDa.
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
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The crystal and molecular structure of 1, 12-dibromododecane, C12H24Br2.
Kulpe S, et al.
Kristall und Technik, 16(3), 349-356 (1981)
A M Badawi et al.
Bioorganic & medicinal chemistry, 14(24), 8661-8665 (2006-09-16)
A novel series of azobenzene isothiouronium salts of different alkyl chains (propyl, hexyl and dodecyl) were synthesized by reaction of 4-((4-methylphenyl)azo)phenol with 1,3-dibromopropane, 1,6-dibromohexane and 1,12-dibromododecane, respectively. These salts were reacted with copper (II) halide to give their corresponding metallo
Sean M Ramirez et al.
Macromolecular bioscience, 9(11), 1127-1134 (2009-07-29)
Novel tboc-protected ionenes with M(w) exceeding 30 kDa were prepared from the step-growth polymerization of tert-butyl bis[3-(dimethylamino)propyl]carbamate and 1,12-dibromododecane. The protected ionenes yielded pH-sensitive, protonatable ionenes with pK(a) approximately 6.6 for the conjugate acid of the protonated secondary amine. Polyplexes