34775
2,6-Di-tert-butyl-4-methylpyridine
purum, ≥97.0% (GC)
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About This Item
Empirical Formula (Hill Notation):
C14H23N
CAS Number:
Molecular Weight:
205.34
EC Number:
253-834-4
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
130503
MDL number:
InChI key
HVHZEKKZMFRULH-UHFFFAOYSA-N
InChI
1S/C14H23N/c1-10-8-11(13(2,3)4)15-12(9-10)14(5,6)7/h8-9H,1-7H3
SMILES string
Cc1cc(nc(c1)C(C)(C)C)C(C)(C)C
grade
purum
assay
≥97.0% (GC)
color
brown
refractive index
n20/D 1.4763 (lit.)
bp
233 °C (lit.)
mp
33-36 °C (lit.)
storage temp.
2-8°C
Physical form
filled as molten mass
Other Notes
Hindered base for glycosidations following a modified Koenigs-Knorr reaction ; Base for the conversion of carbonyls in vinyl triflates with triflic anhydrides
This product has been replaced by 249505-ALDRICH | 2,6-Di-tert-butyl-4-methylpyridine 98%
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
183.2 °F - closed cup
flash_point_c
84 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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D. Crich, S. Sun
The Journal of Organic Chemistry, 62, 1198-1198 (1987)
W.J. Scott et al.
Organic Syntheses, 68, 116-116 (1990)
F.W. Lichtenthaler et al.
European Journal of Organic Chemistry, 3849-3849 (2001)
G. Desmares et al.
Helvetica Chimica Acta, 84, 880-880 (2001)
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