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Merck
CN

34775

Sigma-Aldrich

2,6-Di-tert-butyl-4-methylpyridine

purum, ≥97.0% (GC)

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About This Item

Empirical Formula (Hill Notation):
C14H23N
CAS Number:
Molecular Weight:
205.34
Beilstein:
130503
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
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grade

purum

Assay

≥97.0% (GC)

color

brown

refractive index

n20/D 1.4763 (lit.)

bp

233 °C (lit.)

mp

33-36 °C (lit.)

storage temp.

2-8°C

SMILES string

Cc1cc(nc(c1)C(C)(C)C)C(C)(C)C

InChI

1S/C14H23N/c1-10-8-11(13(2,3)4)15-12(9-10)14(5,6)7/h8-9H,1-7H3

InChI key

HVHZEKKZMFRULH-UHFFFAOYSA-N

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Physical form

filled as molten mass

Other Notes

Hindered base for glycosidations following a modified Koenigs-Knorr reaction ; Base for the conversion of carbonyls in vinyl triflates with triflic anhydrides

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

183.2 °F - closed cup

Flash Point(C)

84 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Certificates of Analysis (COA)

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G. Desmares et al.
Helvetica Chimica Acta, 84, 880-880 (2001)
D. Crich, S. Sun
The Journal of Organic Chemistry, 62, 1198-1198 (1987)
W.J. Scott et al.
Organic Syntheses, 68, 116-116 (1990)
F.W. Lichtenthaler et al.
European Journal of Organic Chemistry, 3849-3849 (2001)

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