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Merck
CN

36685

2-Aminopyridine

PESTANAL®, analytical standard

Synonym(s):

2-AP, 2-Pyridinamine, 2-Pyridylamine

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About This Item

Empirical Formula (Hill Notation):
C5H6N2
CAS Number:
504-29-0
Molecular Weight:
94.11
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
329755451
EC Number:
207-988-4
Beilstein/REAXYS Number:
105785
MDL number:
MFCD00006312

Key Documents

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Product Name

2-Aminopyridine, PESTANAL®, analytical standard

InChI key

ICSNLGPSRYBMBD-UHFFFAOYSA-N

InChI

1S/C5H6N2/c6-5-3-1-2-4-7-5/h1-4H,(H2,6,7)

SMILES string

Nc1ccccn1

grade

analytical standard

product line

PESTANAL®

assay

98-100% (GC)

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

bp

204-210 °C (lit.)

mp

54-58 °C (lit.)

application(s)

agriculture
environmental

format

neat

Quality Level

100

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Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

General description

2-Aminopyridine can be called as structural motifs, which can be encountered in a variety of useful compounds, that includes fluorescent organic materials and therapeutics. It can undergo condensation with an aromatic aldehyde to give the corresponding schiff′s base.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1A

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

197.6 °F - closed cup

flash_point_c

92 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
BCCM3137
BCCK5232
BCCH4977
BCCC8118
BCBW1271

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A novel approach towards design, synthesis and evaluation of some Schiff base analogues of 2-aminopyridine and 2-aminobezothiazole against hepatocellular carcinoma
Chacko S and Samanta S
Biomedicine and Pharmacotherapy, 89, 162-176 (2017)
Pd?PEPPSI?IPentCl: A Useful Catalyst for the Coupling of 2?Aminopyridine Derivatives
Khadra A, et al.
Chemistry?A European Journal , 23, 3206-3212 (2017)
Honggen Wang et al.
Journal of the American Chemical Society, 132(38), 13217-13219 (2010-09-09)
A novel and efficient synthesis of pyrido[1,2-a]benzimidazoles through direct intramolecular aromatic C-H amination of N-aryl-2-aminopyridines has been developed. The reaction, cocatalyzed by Cu(OAc)(2) and Fe(NO(3))(3)·9H(2)O, is carried out in DMF under a dioxygen atmosphere. Diversified pyrido[1,2-a]benzimidazoles containing various substitution patterns
Daniela P Gouvêa et al.
Ultrasonics sonochemistry, 19(6), 1127-1131 (2012-04-10)
The efficient multicomponent synthesis of thiazolidinones from the reaction of arenealdehydes, mercaptoacetic acid and 2-picolilamine or 2-aminopyridine under ultrasound irradiation are reported. The reaction with 2-aminopyridine needs a Lewis acid catalysis to afford the corresponding 2-aryl-3-(pyridin-2-yl)-1,3-thiazolidin-4-ones. All novel compounds were
Thomas Zengeya et al.
Angewandte Chemie (International ed. in English), 51(50), 12593-12596 (2012-11-06)
Peptide nucleic acids containing thymidine and 2-aminopyridine (M) nucleobases form stable and sequence-selective triple helices with double-stranded RNA at physiologically relevant conditions. The M-modified PNA showed unique RNA selectivity by having two orders of magnitude higher affinity for the double-stranded
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