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Merck
CN

37044

Uniconazole

PESTANAL®, analytical standard

Synonym(s):

(E)-(RS)-1-(4-Chlorophenyl)-4,4-dimethyl-2-(1H-1,2,4-triazol-1-yl)pent-1-en-3-ol

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About This Item

Empirical Formula (Hill Notation):
C15H18ClN3O
CAS Number:
Molecular Weight:
291.78
NACRES:
NA.24
PubChem Substance ID:
UNSPSC Code:
41116107
MDL number:
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InChI key

YNWVFADWVLCOPU-MDWZMJQESA-N

SMILES string

CC(C)(C)C(O)C(=C/c1ccc(Cl)cc1) 2cncn2

InChI

1S/C15H18ClN3O/c1-15(2,3)14(20)13(19-10-17-9-18-19)8-11-4-6-12(16)7-5-11/h4-10,14,20H,1-3H3/b13-8+

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

Quality Level

Related Categories

General description

Uniconazole is a vinyl triazole fungicide with plant growth regulatory activity.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Uniconazole may be used as an analytical reference standard for the quantification of the analyte in fruits and vegetables using various chromatographic techniques.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

农药列管产品
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Fast enantiomeric separation of uniconazole and diniconazole by electrokinetic chromatography using an anionic cyclodextrin: Application to the determination of analyte-selector apparent binding constants for enantiomers
Martin-Biosca Y, et al.
Electrophoresis, 21(15), 3240-3248 (2000)
Multi-residue determination of plant growth regulators in apples and tomatoes by liquid chromatography/tandem mass spectrometry
Xue J, et al.
Rapid Communications in Mass Spectrometry, 25(21), 3289-3297 (2011)
Enantiomeric separation of diniconazole and uniconazole by cyclodextrin-modified micellar electrokinetic chromatography
Furuta R and Doi T
Journal of Chromatography A, 676(2), 431-436 (1994)
Peng Wang et al.
Journal of AOAC International, 91(5), 1007-1012 (2008-11-05)
Methods for the enantiomeric quantitative determination of 3 chiral pesticides, paclobutrazol, myclobutanil, and uniconazole, and their residues in soil and water are reported. An effective chiral high-performance liquid chromatographic (HPLC)-UV method using an amylose-tris(3,5-dimethylphenylcarbamate; AD) column was developed for resolving
Yasushi Todoroki et al.
Bioorganic & medicinal chemistry letters, 20(18), 5506-5509 (2010-08-10)
The plant growth-retardant uniconazole (UNI), a triazole inhibitor of gibberellin biosynthetic enzyme (CYP701A), inhibits multiple P450 enzymes including ABA 8'-hydroxylase (CYP707A), a key enzyme in ABA catabolism. Azole P450 inhibitors bind to a P450 active site by both coordinating to

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