379263
2-Methyl-2-butene
technical grade, 90%
Synonym(s):
β-Isoamylene, Amylene
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About This Item
Linear Formula:
CH3CH=C(CH3)2
CAS Number:
Molecular Weight:
70.13
Beilstein:
1361353
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
grade
technical grade
Quality Level
vapor density
2.4 (vs air)
vapor pressure
25.7 psi ( 55 °C)
7.95 psi ( 20 °C)
Assay
90%
form
liquid
expl. lim.
8.7 %
refractive index
n20/D 1.385 (lit.)
bp
35-38 °C (lit.)
mp
−134 °C (lit.)
density
0.662 g/mL at 25 °C (lit.)
SMILES string
C\C=C(\C)C
InChI
1S/C5H10/c1-4-5(2)3/h4H,1-3H3
InChI key
BKOOMYPCSUNDGP-UHFFFAOYSA-N
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General description
2-Methyl-2-butene (β-Isoamylene, Amylene) is a trisubstituted olefin. It acts as guest and forms stable solid host-guest complexes with self-assembled benzophenone bis-urea macrocycles. The effect of active chlorine formulations on photodecomposition of 2-methyl-2-butene has been studied. Its reaction with ozone in gas-phase has been reported to afford carbonym derivatives.
Application
2-Methyl-2-butene may be employed as precursor for peroxyacetyl nitrate for the calibration purposes.
Other Notes
Brass hose adapter Z146811 or brass body mini gas regulator Z513539 is recommended.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 1 - Muta. 2 - STOT SE 3
Target Organs
Central nervous system
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
-4.0 °F
Flash Point(C)
-20 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Michael F Geer et al.
The Journal of organic chemistry, 78(11), 5568-5578 (2013-05-16)
This manuscript investigates how incorporation of benzophenone, a well-known triplet sensitizer, within a bis-urea macrocycle, which self-assembles into a columnar host, influences its photophysical properties and affects the reactivity of bound guest molecules. We further report the generation of a
Yunseok Im et al.
The Science of the total environment, 409(13), 2652-2661 (2011-04-29)
Active chlorine comprising hypochlorite (OCl⁻), hypochlorous acid (HOCl) and chlorine (Cl₂) is the active constituent in bleach formulations for a variety of industrial and consumer applications. However, the strong oxidative reactivity of active chlorine can cause adverse effects on both
Gas-phase reaction of ozone with 2-methyl-2-butene: Dicarbonyl formation from Criegee biradicals.
Grosjean D.
Environmental Science & Technology, 24(9), 1428-1432 (1990)
Confined space-controlled hydroperoxidation of trisubstituted alkenes adsorbed on pentasil zeolites.
Yu-Zhe Chen et al.
The Journal of organic chemistry, 70(12), 4676-4681 (2005-06-04)
Photosensitized oxidation of trialkylalkenes 2-methyl-2-pentene (1), 1-methylcyclohexene (2), trans-3-methyl-2-pentene (3), cis-3-methyl-2-pentene (4), and 2-methyl-2-butene (5) included in the internal framework of Na-ZSM-5 zeolites was investigated. The zeolite samples having adsorbed the alkenes were suspended in isooctane, and the sensitizer, tetraphenylporphyrin
Masataka Ikeda et al.
Scientific reports, 5, 15881-15881 (2015-10-31)
The heart has two major modalities of hypertrophy in response to hemodynamic loads: concentric and eccentric hypertrophy caused by pressure and volume overload (VO), respectively. However, the molecular mechanism of eccentric hypertrophy remains poorly understood. Here we demonstrate that the
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