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Merck
CN

38433

Diisopropoxytitanium bis(acetylacetonate) solution

purum, ~75% in isopropanol

Synonym(s):

Ti(acac)2OiPr2

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About This Item

Linear Formula:
[(CH3)2CHO]2Ti(C5H7O2)2
CAS Number:
17927-72-9
Molecular Weight:
364.26
UNSPSC Code:
12352300
PubChem Substance ID:
329755762
MDL number:
MFCD00000031

Key Documents

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InChI

1S/2C5H8O2.2C3H7O.Ti/c2*1-4(6)3-5(2)7;2*1-3(2)4;/h2*3,6H,1-2H3;2*3H,1-2H3;/q;;2*-1;+4/p-2/b2*4-3+;;;

SMILES string

CC(C)O[Ti](OC(C)C)(O\C(C)=C\C(C)=O)O\C(C)=C\C(C)=O

InChI key

OVSGBKZKXUMMHS-VVDZMTNVSA-L

grade

purum

reaction suitability

core: titanium, reagent type: catalyst

concentration

~75% in isopropanol

density

1.00 g/mL at 20 °C

signalword

Danger

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 2 - STOT SE 3

target_organs

Central nervous system

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

53.6 °F - closed cup

flash_point_c

12 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

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Jin-Wook Lee et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 15(12), 2595-2603 (2014-05-28)
A dichlorobenzene-functionalized hole-transporting material (HTM) is developed for a CH3NH3PbI3-based perovskite solar cell. Notwithstanding the similarity of the frontier molecular orbital energy levels, optical properties, and hole mobility between the functionalized HTM [a polymer composed of 2'-butyloctyl-4,6-dibromo-3-fluorothieno[3,4-b]thiophene-2-carboxylate (TT-BO), 3',4'-dichlorobenzyl-4,6-dibromo-3-fluorothieno[3,4-b]thiophene-2-carboxylate (TT-DCB)
Jin-Wook Lee et al.
Advanced materials (Deerfield Beach, Fla.), 26(29), 4991-4998 (2014-06-14)
Perovskite solar cells with power conversion efficiencies exceeding 16% at AM 1.5 G one sun illumination are developed using the black polymorph of formamidnium lead iodide, HC(NH2)2 PbI3 . Compared with CH3 NH3 PbI3 , HC(NH2 )2 PbI3 extends its
Hyun-Woo Kang et al.
Faraday discussions, 176, 287-299 (2014-11-20)
The effect of double blocking layers on the Sb(2)S(3)-sensitized all solid state solar cell are investigated. Thin layers of ZrO(2) (blocking layer 1, BL1) and ZnS (blocking layer 2, BL2) are introduced at the TiO(2)/Sb(2)S(3) and Sb(2)S(3)/hole transporting material (HTM)

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