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Merck
CN

426326

Tetrabutylammonium hydroxide solution

ACS reagent, 1.0 M in H2O

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About This Item

Linear Formula:
(CH3CH2CH2CH2)4N(OH)
CAS Number:
2052-49-5
Molecular Weight:
259.47
PubChem Substance ID:
24866696
UNSPSC Code:
12352100
Beilstein/REAXYS Number:
3571228
MDL number:
MFCD00009425

Key Documents

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SMILES string

[OH-].CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/C16H36N.H2O/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H2/q+1;/p-1

InChI key

VDZOOKBUILJEDG-UHFFFAOYSA-M

grade

ACS reagent

form

liquid

concentration

1.0 M in H2O, 1.0 M±0.02 M (ACS specification)

impurities

≤0.2% tributylamine

color

APHA: ≤30

refractive index

n20/D 1.389

density

1 g/mL at 25 °C

anion traces

carbonate (CO32-): ≤0.1%, chloride (Cl-): ≤0.08%

cation traces

K: ≤2 ppm, Na: ≤2 ppm

Quality Level

200

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General description

Tetrabutylammonium hydroxide (TBAH) solution it is a strong organic base. It enables the dispersion of fatty acids in water at room temperature which allows the formation of emulsions and foams. TBAH is used as a titrant in the potentiometric titration of weak acids in non-aqueous media.

Application

Phase-transfer catalyst.
Tetrabutylammonium hydroxide solution may be used in the following processes:
  • Synthesis of carbon doped TiO2 (titanium dioxide).
  • Synthesis of C60 derivative-hydroxylated fullerene epoxide.
  • As a hydrolysis controlling agent in the prearation of TiO2 sol.

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
STBG0649V
STBF8408V
BCBM9041V
BCBH6728V
BCBL2538V

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Natural monocrystalline pyrite as a sensor in non-aqueous solution: Part I: Potentiometric titration of weak acids in, N,N-dimethylformamide, methylpyrrolidone and pyridine.
Mihajlovic LV, et al.
Talanta, 64(4), 879-886 (2004)
Daylight photocatalysis by carbon-modified titanium dioxide.
Sakthivel S and Kisch H.
Angewandte Chemie (International Edition in English), 42(40), 4908-4911 (2003)
Journal of the Chemical Society. Chemical Communications, 1045-1045 (1990)
Low temperature deposition of TiO2 thin films on polyvinyl alcohol fibers with photocatalytical and antibacterial activities.
Liuxue Z, et al.
Applied Surface Science, 254(6), 1771-1774 (2008)
Synthesis and characterization of hydroxylated fullerene epoxide-an intermediate for forming fullerol.
Li T, et al.
Journal of Central South University of Technology, 6(1), 35-36 (1999)
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