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Merck
CN

42860

1,5-Diphenylcarbazide

purum p.a., ACS reagent, for the determination of Cd, Cr, Mg, SO4 and others, ≥97.0% (HPLC)

Synonym(s):

1,5-Diphenylcarbohydrazide, sym.-Diphenylcarbazide

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About This Item

Linear Formula:
C6H5NHNHCONHNHC6H5
CAS Number:
Molecular Weight:
242.28
EC Number:
205-403-7
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
752039
MDL number:
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grade

ACS reagent, purum p.a.

assay

≥97.0% (HPLC)

quality

for the determination of Cd, Cr, Mg, SO4 and others

technique(s)

titration: suitable

mp

170-175 °C (lit.), 171-175 °C

SMILES string

O=C(NNc1ccccc1)NNc2ccccc2

InChI

1S/C13H14N4O/c18-13(16-14-11-7-3-1-4-8-11)17-15-12-9-5-2-6-10-12/h1-10,14-15H,(H2,16,17,18)

InChI key

KSPIHGBHKVISFI-UHFFFAOYSA-N

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Other Notes

Reagent for the determination of chromium and other metals

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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K.L. Cheng et al.
Handbook of Organic Analytical Reagents null
Deng-ming Sun
Guang pu xue yu guang pu fen xi = Guang pu, 23(1), 196-198 (2003-08-28)
In this paper, the reaction mechanism of the system of thallium (III)-copper(II)-ethylenediaminete-traacetate-hydrogen peroxide-diphenylcarbazide has been studied by spectrophotometric method. The experimental results show that the reaction mechanism of the system is based on the replacement of copper(II) by thallium (III)
B K Semin et al.
FEBS letters, 375(3), 223-226 (1995-11-20)
The interaction of Fe(II) and Fe(III) with the 'high-affinity Mn-binding site' in Mn-depleted photosystem II (PSII) was investigated using diphenilcarbazide (DPC)/2,6-dichlorophenol-indophenol (DCIP) inhibition assay. Fe(III) was ineffective in the inhibition of DPC-DCIP reaction while Fe(II) decreased the rate of DCIP
Sivanildo da Silva Borges et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 18(12), 1361-1366 (2002-12-28)
Oxidation of Cr(III) during sonication in carbonated aqueous solutions saturated with CCl4 leads to the quantitative formation of Cr(VI) and provides a simple and rapid method for spectrophotometric chromium determination with 1,5-diphenylcarbazide. The key to this method is the production
M L Ghirardi et al.
Biochemistry, 35(6), 1820-1828 (1996-02-13)
The inhibition of DPC-mediated DCIP photoreduction by exogenous MnCl2 in Tris-treated photosystem II (PSII) membrane fragments has been used to probe for amino acids on the PSII reaction center proteins, including D1His337, that provide ligands for binding manganese [Preston, C.

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