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Merck
CN

42960

Diphenyl disulfide

technical, ≥97.0% (HPLC)

Synonym(s):

Phenyl disulfide

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About This Item

Linear Formula:
C6H5SSC6H5
CAS Number:
Molecular Weight:
218.34
EC Number:
212-926-4
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
639794
MDL number:
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InChI key

GUUVPOWQJOLRAS-UHFFFAOYSA-N

InChI

1S/C12H10S2/c1-3-7-11(8-4-1)13-14-12-9-5-2-6-10-12/h1-10H

SMILES string

S(Sc1ccccc1)c2ccccc2

grade

technical

assay

≥97.0% (HPLC)

mp

58-60 °C

Other Notes

Reagent for the α-phenylsulfenylation of carbonyl compounds
This product has been replaced by 169021-ALDRICH | Phenyl disulfide 99%

pictograms

Exclamation markEnvironment

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Molecular modeling and enzyme kinetics indicate a novel mechanism for mammalian 5-lipoxygenase.
R W Egan et al.
Advances in prostaglandin, thromboxane, and leukotriene research, 17A, 69-74 (1987-01-01)
J I Rossato et al.
Neurochemical research, 27(4), 297-303 (2002-04-18)
Ebselen (2-phenyl- 1,2-benzisoselenazole-3 (2H)-one) is a seleno-organic compound with antioxidant properties, and anti-inflammatory actions. Recently, ebselen improved the outcome of acute ischemic stroke in humans. In the present study, the potential antioxidant capacity of organochalcogenide compounds diphenyl diselenide (PhSe)2, diphenyl
C W Nogueira et al.
Toxicology, 191(2-3), 169-178 (2003-09-11)
Organochalcogens are important intermediates and useful reagents in organic synthesis, which can increase human exposure risk to these chemicals in the workplace. As well, there are a number of reported cases of acute toxicity following organochalcogen ingestion of vitamins and
E W Srikendari et al.
Redox report : communications in free radical research, 6(3), 191-193 (2001-08-29)
The aim of this study was to determine whether disulfides could serve as protective antioxidants for alpha-tocopherol or vice versa. The chosen reaction system was a co-oxidation of the model compound of alpha-tocopherol, 2,2,5,7,8-pentamethyl-6-chromanol (PMC), and diphenyl disulfide (1) by
Yutaka Nishiyama et al.
Molecules (Basel, Switzerland), 14(9), 3367-3375 (2009-09-29)
It was found that cesium carbonate has a unique catalytic ability on the reaction of carbonyl compounds with diphenyl diselenide to give the corresponding alpha-phenylseleno carbonyl compounds in moderate to good yields. Similarly, the alpha-phenylthiolation of carbonyl compounds with diphenyl

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