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Merck
CN

43800

Dithiooxamide

for spectrophotometric det. of Cu, Os, Bi, Co, Cu, Fe, Ni, Os, Pt, Ru, ≥98.5%

Synonym(s):

Dithiooxalic diamide, Rubeanic acid

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About This Item

Linear Formula:
NH2CSCSNH2
CAS Number:
Molecular Weight:
120.20
EC Number:
201-203-9
UNSPSC Code:
41116105
PubChem Substance ID:
Beilstein/REAXYS Number:
605577
MDL number:
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assay

≥98.5% (N), ≥98.5%

quality

for spectrophotometric det. of Cu, Os, Bi, Co, Cu, Fe, Ni, Os, Pt, Ru

technique(s)

UV/Vis spectroscopy: suitable

ign. residue

≤0.1%

mp

≥300 °C (lit.)

SMILES string

NC(=S)C(N)=S

InChI

1S/C2H4N2S2/c3-1(5)2(4)6/h(H2,3,5)(H2,4,6)

InChI key

OAEGRYMCJYIXQT-UHFFFAOYSA-N

General description

Dithiooxamide is an organic compound which is basically a sulfur analog of oxamide. It is mostly used as metal deactivators and vulcanization accelerators. It forms stable metal complexes which acts as colour sources in duplicating processes.

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Regulatory Information

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Preparation of Dithiooxamide Derivatives.
HURD, RICHARD N., et al.
The Journal of Organic Chemistry, 26, 3980-3987 (1961)
Casey W Quinn et al.
Environmental science & technology, 52(6), 3567-3573 (2018-02-23)
Metal contamination of natural and drinking water systems poses hazards to public and environmental health. Quantifying metal concentrations in water typically requires sample collection in the field followed by expensive laboratory analysis that can take days to weeks to obtain
Incorporation of dithiooxamide as a complexing agent into cellulose for the removal and pre-concentration of Cu (II) and Cd (II) ions from natural water samples.
Jorgetto, A. O., et al.
Applied Surface Science, 264, 368-374 (2013)
Ayşen Demir Mülazımoğlu et al.
Sensors (Basel, Switzerland), 12(4), 3916-3928 (2012-06-06)
Electrochemical oxidation of quercetin, as an important biological molecule, has been studied in non-aqueous media using cyclic voltammetry, electrochemical impedance spectroscopy and scanning electron microscopy. To investigate the electrochemical properties of quercetin, an important flavonoid derivative, on a different surface
Yurii A Simonov et al.
Organic & biomolecular chemistry, 1(16), 2922-2929 (2003-09-13)
The hydrogen-bonding networks for seven new binary compounds of dithiooxamide, (NH2CS)2 (dtox) and dithiobiurea (NH2CSNH)2 (dtur) with crown ethers, 18-crown-6 (18C6), 15-crown-5 (15C5), 12-crown-4 (12C4), cis-syn-cis-(DCHA), and cis-anti-cis-(DCHB) isomers of dicyclohexyl-18 -crown-6 are discussed. (15C5.dtox), (18C6.dtur) and (DCHB.dtur) afford one-dimensional

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