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Merck
CN

45804

Triphenylene

analytical standard

Synonym(s):

9,10-Benzophenanthrene

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About This Item

Empirical Formula (Hill Notation):
C18H12
CAS Number:
Molecular Weight:
228.29
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
205-922-9
Beilstein/REAXYS Number:
1342908
MDL number:
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InChI key

SLGBZMMZGDRARJ-UHFFFAOYSA-N

InChI

1S/C18H12/c1-2-8-14-13(7-1)15-9-3-4-11-17(15)18-12-6-5-10-16(14)18/h1-12H

SMILES string

c1ccc2c(c1)c3ccccc3c4ccccc24

grade

analytical standard

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

bp

438 °C (lit.)

mp

195-198 °C (lit.)

application(s)

environmental

format

neat

Quality Level

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General description

Triphenylene belongs to the class of polycyclic aromatic hydrocarbons, which is commonly employed as a substrate for use as a precursor for the synthesis of graphenes, carbon nanotubes, buckminsterfullerenes as well as polycyclic heteroaromatics.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Triphenylene may be used as an analytical reference standard for the quantification of the analyte in environmental samples using gas chromatography technique.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

pictograms

CorrosionEnvironment

signalword

Danger

hcodes

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

Storage Class

11 - Combustible Solids

wgk

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Analysis of polycyclic aromatic hydrocarbons (PAHs) in environmental samples: a critical review of gas chromatographic (GC) methods
Poster.LD, et al.
Analytical and Bioanalytical Chemistry, 386(4), 859-881 (2006)
Analysis of polycyclic aromatic hydrocarbons (PAHs) in environmental samples: a critical review of gas chromatographic (GC) methods
Prasad RP, et al.
Journal of Chemical Sciences (Bangalore), 126(5), 1311-1321 (2014)
Fabián Vaca Chávez et al.
The journal of physical chemistry. B, 116(8), 2339-2346 (2012-02-23)
The Larmor frequency and temperature dependence of the proton nuclear magnetic resonance (NMR) spin-lattice relaxation time was measured in the isotropic and columnar phases of both chain-end fluorinated triphenylene disk-like and fully hydrogenated molecules. In the columnar phase, the results
Mahuya Bagui et al.
The journal of physical chemistry. A, 115(9), 1579-1592 (2011-02-12)
A donor-acceptor charge transfer system based on two discotic mesogens has been synthesized. The donor is either a triphenylene (POG0) or a triphenylene-based conjugated dendron (POG1), while the acceptor is a perylene diimide (PDI) core. The donors are covalently linked
Vandana Bhalla et al.
Langmuir : the ACS journal of surfaces and colloids, 27(24), 15275-15281 (2011-11-15)
Triphenylene-based discotic liquid crystal 3 bearing 1,2,3-triazole groups has been synthesized using "click" chemistry. Discotic mesogen 3 has good thermal stability, and incorporation of triazole groups results in stabilization of columnar mesophases down to room temperature and formation of organogels

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