47725
1-Formylpiperidine
purum, ≥99.0% (GC)
Synonym(s):
N-Carbaldehyde piperidine, NFP, Piperidine-1-carboxaldehyde
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About This Item
Empirical Formula (Hill Notation):
C6H11NO
CAS Number:
Molecular Weight:
113.16
EC Number:
219-986-0
UNSPSC Code:
12352100
MDL number:
Beilstein/REAXYS Number:
107697
vapor pressure
0.1 mmHg ( 25 °C)
grade
purum
assay
≥99.0% (GC)
refractive index
n20/D 1.484 (lit.), n20/D 1.485
bp
222 °C (lit.)
density
1.019 g/mL at 25 °C (lit.)
SMILES string
[H]C(=O)N1CCCCC1
InChI
1S/C6H11NO/c8-6-7-4-2-1-3-5-7/h6H,1-5H2
InChI key
FEWLNYSYJNLUOO-UHFFFAOYSA-N
Application
Reactant for:
- Direct amidation of azoles with formamides via metal-free C-H activation in the presence of tert-butyl perbenzoate
- Vilsmeier-type reactions of pyrazoles with amides in the presence of phosphorous oxychloride
- CO-free aminocarbonylation of N-substituted formamides with aryl iodides/bromides catalyzed by palladium acetate and Xantphos for synthesis of arylamides
- Synthesis of alternating copolymers for organic photovoltaic applications
- One-pot double functionalization of π-deficient heterocyclic lithium reagents
- Synthesis of thermally stable piezofluorochromic aggregation-induced emission compounds
Other Notes
Used in formyl transfer to Grignard reagents
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G.A. Olah et al.
Organic Syntheses, 64, 114-114 (1986)
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