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About This Item
Linear Formula:
NH2CH2CONH2 · HCl
CAS Number:
Molecular Weight:
110.54
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
216-789-1
Beilstein/REAXYS Number:
3554199
MDL number:
Assay:
≥99.0% (AT)
Form:
solid
Quality Level
assay
≥99.0% (AT)
form
solid
pKa (20 °C)
8.20
solubility
H2O: 0.1 g/mL, clear, colorless
anion traces
sulfate (SO42-): ≤50 mg/kg
cation traces
Ca: ≤10 mg/kg, Cd: ≤5 mg/kg, Co: ≤5 mg/kg, Cr: ≤5 mg/kg, Cu: ≤5 mg/kg, Fe: ≤5 mg/kg, K: ≤50 mg/kg, Mg: ≤5 mg/kg, Mn: ≤5 mg/kg, Na: ≤50 mg/kg, Ni: ≤5 mg/kg, Pb: ≤5 mg/kg, Zn: ≤5 mg/kg
λ
0.5 M in H2O
UV absorption
λ: 260 nm Amax: 0.1
functional group
amide, amine
SMILES string
Cl.NCC(N)=O
InChI
1S/C2H6N2O.ClH/c3-1-2(4)5;/h1,3H2,(H2,4,5);1H
InChI key
WKNMKGVLOWGGOU-UHFFFAOYSA-N
Application
Glycinamide hydrochloride may be used in the synthesis of [M(glycinamidato-N,N′)(ptpy)2] where ptpy = 2-(p-tolyl)pyridinato) and M= Rh or Ir.
It may be used in the synthesis of the following glycinamide-based imidazolidinones:
It may be used in the synthesis of the following glycinamide-based imidazolidinones:
- (±)-2-(2-phenylpropyl)imidazolidin-4-one
- (±)-2-(2,4,4-trimethylpentyl)imidazolidin-4-one
- (±)-2-[(R)-2,6-dimethyl-5-heptenyl]imidazolidin-4-one
- (5R,6S,9R)-6-isopropyl-9-methyl-1,4-diazaspiro[4.5]decan-2-one
- (5S,6S,9R)-6-isopropyl-9-methyl-1,4-diazaspiro[4.5]decan-2-one
- (±)-2-methyl-2-pentylimidazolidin-4-one
- (±)-2-ethyl-2-(2-methylbutyl)imidazolidin-4-one
- (±)-2-(undecan-2-yl)imidazolidin-4-one
- (±)-2-pentylimidazolidin-4-one
- 2-(2,4-dimethylcyclohex-3-en-1-yl)imidazolidin-4-one
Other Notes
Use in peptide coupling.
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Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Preparation of Imidazolidin-4-ones and Their Evaluation as Hydrolytically Cleavable Precursors for the Slow Release of Bioactive Volatile Carbonyl Derivatives.
Trachsel A, et al.
European Journal of Organic Chemistry, 2012(14), 2837-2854 (2012)
N.J. Miles et al.
Journal of the Chemical Society. Perkin Transactions 1, 2299-2299 (1985)
Synthesis and Characterization of New Bis-Cyclometalated Rhodium and Iridium Complexes Containing the Glycinamidato Ligand.
Graf M, et al.
Zeitschrift fur Anorganische und Allgemeine Chemie, 639(7), 1117-1121 (2013)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 50070-10G | 04061838351364 |
| 50070-50G | 04061832422565 |