52550
(R)-(−)-Hexahydromandelic acid
purum, ≥97.5% (sum of enantiomers, HPLC)
Synonym(s):
(R)-(−)-Cyclohexylhydroxyacetic acid
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About This Item
Linear Formula:
C6H11CH(OH)CO2H
CAS Number:
Molecular Weight:
158.19
PubChem Substance ID:
UNSPSC Code:
12352000
Beilstein/REAXYS Number:
3196809
MDL number:
SMILES string
O[C@H](C1CCCCC1)C(O)=O
InChI
1S/C8H14O3/c9-7(8(10)11)6-4-2-1-3-5-6/h6-7,9H,1-5H2,(H,10,11)/t7-/m1/s1
InChI key
RRDPWAPIJGSANI-SSDOTTSWSA-N
grade
purum
assay
≥97.5% (sum of enantiomers, HPLC)
optical activity
[α]20/D −23±1°, c = 1% in acetic acid
mp
127-129 °C (lit.), 127-130 °C
storage temp.
2-8°C
Other Notes
Chiral auxiliary substance for enantioselective aldol-condensations via boron enolates
Regulatory Information
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R.D. Larsen et al.
Journal of the American Chemical Society, 111, 7650-7650 (1989)
D. Boschelli et al.
Tetrahedron Letters, 25, 3395-3395 (1984)
Journal of the American Chemical Society, 104, 5521-5521 (1982)
S. Massamune et al.
Journal of the American Chemical Society, 103, 1566-1566 (1981)
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