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Merck
CN

53490

Sigma-Aldrich

1-Methylpiperidine solution

BioReagent, suitable for protein sequencing, ~40% in 1-butanol

Synonym(s):

N-Methylpiperidine

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About This Item

Empirical Formula (Hill Notation):
C6H13N
CAS Number:
626-67-5
Molecular Weight:
99.17
Beilstein:
1560282
MDL number:
MFCD00006491
UNSPSC Code:
12352200
PubChem Substance ID:
329757951

Key Documents

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product line

BioReagent

concentration

~40% in 1-butanol

refractive index

n20/D 1.406

suitability

suitable for protein sequencing

storage temp.

−20°C

SMILES string

CN1CCCCC1

InChI

1S/C6H13N/c1-7-5-3-2-4-6-7/h2-6H2,1H3

InChI key

PAMIQIKDUOTOBW-UHFFFAOYSA-N

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Packaging

Special packaging for direct use in common sequencers.

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3

Target Organs

Central nervous system, Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

82.4 °F - closed cup

Flash Point(C)

28 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Nithyanandhan Jayaraj et al.
Langmuir : the ACS journal of surfaces and colloids, 25(24), 13820-13832 (2010-06-22)
Supramolecular complexation behavior of cucurbiturils with paramagnetic nitroxide spin probes was examined by (1)H NMR, X-ray diffraction studies of crystals, computation, and EPR. Both cucurbit[7]uril (CB7) and cucurbit[8]uril (CB8) form a 1:1 complex with 4-(N,N,N-trimethylammonium)-2,2,6,6-tetramethylpiperidinyl-N-oxy bromide (CAT1). The structure of
A Kolocouris et al.
The Journal of organic chemistry, 66(15), 4989-4997 (2001-07-21)
When a 1-adamantyl or a 2-adamantyl substituent is introduced at the 2-position in N-methylpiperidine, four different chair conformations are possible. Experimental observation using dynamic NMR spectroscopy and molecular mechanics calculations agree that the chair conformation with an equatorial adamantyl group
Francisc Potmischil et al.
Magnetic resonance in chemistry : MRC, 45(3), 231-235 (2007-01-16)
The (15)N chemical shifts of 13 N-methylpiperidine-derived mono-, bi- and tricycloaliphatic tertiary amines, their methiodides and their N-epimeric pairs of N-oxides were measured, and the contributions of specific structural parameters to the chemical shifts were determined by multilinear regression analysis.
[The mechanism of reverse inhibition of cholinesterases by thionphosphonates].
N N Kovalev et al.
Izvestiia Akademii nauk SSSR. Seriia biologicheskaia, (6)(6), 926-929 (1988-11-01)
[Studies of pyrazine derivatives. XXV. Synthesis and the tuberculostatic activity of the products of reaction of 5-(6-methoxy- and 5-(6 morpholinopyrazinyl)-1,3,4-oxadiazol-2-thione with amines].
D Pancechowska-Ksepko et al.
Acta poloniae pharmaceutica, 45(5), 373-379 (1988-01-01)
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