55640
Cyclohexanemethanol
purum, ≥95.0% (GC)
Synonym(s):
(Hydroxymethyl)cyclohexane, Cyclohexyl methanol, Hexahydrobenzyl alcohol, NSC 5288
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About This Item
Linear Formula:
C6H11CH2OH
CAS Number:
Molecular Weight:
114.19
EC Number:
202-857-8
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
773712
MDL number:
InChI key
VSSAZBXXNIABDN-UHFFFAOYSA-N
InChI
1S/C7H14O/c8-6-7-4-2-1-3-5-7/h7-8H,1-6H2
SMILES string
OCC1CCCCC1
grade
purum
assay
≥95.0% (GC)
refractive index
n20/D 1.464, n20/D 1.465 (lit.)
bp
181 °C (lit.)
density
0.928 g/mL at 25 °C (lit.)
Storage Class
10 - Combustible liquids
wgk
WGK 1
flash_point_f
170.6 °F - closed cup
flash_point_c
77 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Yasunori Okada et al.
Organic letters, 9(8), 1573-1576 (2007-03-16)
[reaction: see text] Ethyl 1-thio-2,3,4,6-tetrakis-O-triisopropylsilyl-beta-d-glucopyranoside, ethyl 6-O-benzyl-1-thio-2,3,4-tris-O-triisopropylsilyl-beta-d-glucopyranoside, and ethyl 6-O-pivaloyl-1-thio-2,3,4-tris-O-triisopropylsilyl-beta-d-glucopyranoside induced highly beta-selective O-glucosidations. Among them, the 6-O-pivaloylated substrate provided the best selectivity up to alpha/beta = 3:97 with cyclohexylmethanol, and the substrate was used for glucosidations with secondary and
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