57690
3-Iodoaniline
purum, ≥97.0% (NT)
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About This Item
Linear Formula:
IC6H4NH2
CAS Number:
Molecular Weight:
219.02
EC Number:
210-922-7
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
636058
MDL number:
InChI key
FFCSRWGYGMRBGD-UHFFFAOYSA-N
InChI
1S/C6H6IN/c7-5-2-1-3-6(8)4-5/h1-4H,8H2
SMILES string
Nc1cccc(I)c1
grade
purum
assay
≥97.0% (NT)
form
liquid
color
clear yellow
refractive index
n20/D 1.682 (lit.)
bp
145-146 °C/15 mmHg (lit.)
mp
21-24 °C (lit.)
density
1.821 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Regulatory Information
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Karsten Franke et al.
Environmental science & technology, 42(11), 4083-4087 (2008-07-02)
A new method is described for radiolabeling humic substances (HS) with iodine radioisotopes. The method radiolabels the electron-rich aromatic moieties of HS with the 3-[125I]iodobenzenediazonium ion via azocoupling. The method uses four steps: (i) 3-aminobenzenetrimethylstannane is synthesized and isolated by
Karin Dooleweerdt et al.
Organic letters, 11(1), 221-224 (2008-11-28)
A Pd-catalyzed, one-pot, two-step synthesis of 2-amidoindoles from ynamides and o-iodoanilines is reported. A key highlight of this sequence is that after the Sonogashira reaction, intramolecular cyclization to the indole occurs spontaneously without activation of the alkyne.
L A Khawli et al.
International journal of radiation applications and instrumentation. Part B, Nuclear medicine and biology, 19(3), 297-301 (1992-04-01)
Biotinyl-m-[125I]iodoanilide (BIA) was synthesized by coupling biotin to m-[125I]iodoaniline via a mixed anhydride reaction. m-[125I]Iodoaniline was produced from the tin precursor, which was prepared using a palladium catalyzed reaction of hexabutylditin with m-bromoaniline. The radioiodinated BIA derivative is characterized by
Dimitrios E Lizos et al.
Organic & biomolecular chemistry, 1(1), 117-122 (2003-08-22)
A brief, efficient and economical synthesis of the spiropyrrolidinyloxindoles, horsfiline and coerulescine, has been achieved, starting from itaconic acid and, respectively, p-anisidine or o-iodoaniline. Tandem radical cyclisation of iodoaryl alkenyl azides is the key step in both syntheses.
Toshio Nishikawa et al.
Bioscience, biotechnology, and biochemistry, 66(10), 2273-2278 (2002-11-27)
An alpha-C-iodoethynylglucose derivative was coupled with an L-serine-derived zinc-copper reagent to give alpha-C-glucosylpropargyl glycine, which underwent palladium catalyzed-heteroannulation with o-iodoaniline to give not alpha-C-glucosyl-tryptophan but alpha-C-glucosyl-iso-tryptophan. This is the first observation of complete reverse regioselectivity to Larock's proposal.
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