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Merck
CN

58070

N-Iodosuccinimide

purum, ≥97.0% (RT)

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About This Item

Empirical Formula (Hill Notation):
C4H4INO2
CAS Number:
Molecular Weight:
224.98
EC Number:
208-221-6
UNSPSC Code:
12352101
PubChem Substance ID:
Beilstein/REAXYS Number:
113917
MDL number:
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InChI key

LQZMLBORDGWNPD-UHFFFAOYSA-N

InChI

1S/C4H4INO2/c5-6-3(7)1-2-4(6)8/h1-2H2

SMILES string

IN1C(=O)CCC1=O

grade

purum

assay

≥97.0% (RT)

mp

~200 °C (dec.), 202-206 °C (lit.)

storage temp.

2-8°C

Other Notes

Reagent for the oxidimetric titration of sulfur functions ; Reagent for oxidations ; Reagent for iodinations

signalword

Warning

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Muta. 2 - Skin Irrit. 2 - Skin Sens. 1B

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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A. Speicher, T. Eicher
J. Prakt. Chem./Chem.-Ztg., 340, 278-278 (1998)
A. Fiumana et al.
The Journal of Organic Chemistry, 62, 5623-5623 (1997)
V.K. Chaikovskii et al.
Russ. J. Org. Chem., 37, 1503-1503 (2001)
G.A. Olah et al.
The Journal of Organic Chemistry, 58, 3194-3194 (1993)
A Srivastava
Talanta, 26(10), 917-920 (1979-10-01)
Titrimetric determination of thioureas, thiols, xanthates and dithiocarbamates with N-iodosuccinimide (NIS) is described. The method for xanthate can be applied to carbon disulphide (converted into xanthate with potassium ethoxide). Acidic and non-aqueous solutions of the oxidizing agent are stable. The

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