Skip to Content
Merck
CN

59439

1,2-O-Isopropylidene-α-D-glucofuranose

puriss., ≥98.5% (TLC)

Synonym(s):

Monoacetone glucose

Sign In to View Organizational & Contract Pricing.

Select a Size

Change View

About This Item

Empirical Formula (Hill Notation):
C9H16O6
CAS Number:
Molecular Weight:
220.22
EC Number:
242-420-9
UNSPSC Code:
12352200
MDL number:
Beilstein/REAXYS Number:
82670
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist


grade

puriss.

assay

≥98.5% (TLC)

optical activity

[α]20/D −11.7±0.5°, c = 2% in H2O

mp

158-161 °C

storage temp.

2-8°C

SMILES string

CC1(C)O[C@H]2O[C@H]([C@H](O)CO)[C@H](O)[C@H]2O1

InChI

1S/C9H16O6/c1-9(2)14-7-5(12)6(4(11)3-10)13-8(7)15-9/h4-8,10-12H,3H2,1-2H3/t4-,5+,6-,7-,8-/m1/s1

InChI key

BGGCXQKYCBBHAH-OZRXBMAMSA-N

Other Notes

Partially protected D-glucofuranose, an important chiral building block. It can e.g. be selectively derivatized at the primary 6-OH group, or oxidatively cleaved to a pentodialdose derivative; Direct transformation to the 5,6-anhydro compound (Mitsunobu reaction); Preparation of the 3,5-O-benzylidene derivative


Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Information

新产品

This item has



Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

It looks like we've run into a problem, but you can still download Certificates of Analysis from our Documents section.

If you need assistance, please contact Customer Support

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library



D. Hendry et al.
Tetrahedron Letters, 28, 4597-4597 (1987)
S. Hanessian
Total Synthesis of Natural Products null
S. Achab et al.
Journal of the Chemical Society. Chemical Communications, 391-391 (1983)