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About This Item
Empirical Formula (Hill Notation):
C9H16O6
CAS Number:
Molecular Weight:
220.22
EC Number:
242-420-9
UNSPSC Code:
12352200
MDL number:
Beilstein/REAXYS Number:
82670
grade
puriss.
assay
≥98.5% (TLC)
optical activity
[α]20/D −11.7±0.5°, c = 2% in H2O
mp
158-161 °C
storage temp.
2-8°C
SMILES string
CC1(C)O[C@H]2O[C@H]([C@H](O)CO)[C@H](O)[C@H]2O1
InChI
1S/C9H16O6/c1-9(2)14-7-5(12)6(4(11)3-10)13-8(7)15-9/h4-8,10-12H,3H2,1-2H3/t4-,5+,6-,7-,8-/m1/s1
InChI key
BGGCXQKYCBBHAH-OZRXBMAMSA-N
Other Notes
Partially protected D-glucofuranose, an important chiral building block. It can e.g. be selectively derivatized at the primary 6-OH group, or oxidatively cleaved to a pentodialdose derivative; Direct transformation to the 5,6-anhydro compound (Mitsunobu reaction); Preparation of the 3,5-O-benzylidene derivative
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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D. Hendry et al.
Tetrahedron Letters, 28, 4597-4597 (1987)
S. Hanessian
Total Synthesis of Natural Products null
S. Achab et al.
Journal of the Chemical Society. Chemical Communications, 391-391 (1983)