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Merck
CN

59735

(S)-4-Isopropyl-3-propionyl-2-oxazolidinone

purum, ≥97.0% (sum of enantiomers, GC)

Synonym(s):

(S)-3-Propionyl-4-isopropyl-2-oxazolidinone

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About This Item

Empirical Formula (Hill Notation):
C9H15NO3
CAS Number:
Molecular Weight:
185.22
PubChem Substance ID:
UNSPSC Code:
12352000
MDL number:
Beilstein/REAXYS Number:
3542849
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grade

purum

assay

≥97.0% (sum of enantiomers, GC)

optical activity

[α]20/D +94±2°, c = 8.7% in methylene chloride

refractive index

n20/D 1.465

bp

102-106 °C/0.75 mmHg (lit.)

density

1.094 g/mL at 20 °C (lit.)

storage temp.

2-8°C

SMILES string

CCC(=O)N1[C@H](COC1=O)C(C)C

Other Notes

Chiral derivative of propionic acid used in highly enantioselective aldol, alkylation and acylation reactions

Regulatory Information

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R.M. DiPardo et al.
Tetrahedron Letters, 24, 4805-4805 (1983)
Topics in Stereochemistry, 13, 1-1 (1982)
D.A. Evans et al.
Journal of the American Chemical Society, 104, 1737-1737 (1982)
D.A. Evans et al.
Journal of the American Chemical Society, 106, 1154-1154 (1984)
D.A. Evans et al.
Journal of the American Chemical Society, 103, 2127-2127 (1981)

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