60244
Potassium fluoride on aluminum oxide
extent of labeling: ~5.5 mmol/g F- loading
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About This Item
Linear Formula:
KF-Al2O3
UNSPSC Code:
23151817
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3902818
InChI
1S/FH.K/h1H;/q;+1/p-1
SMILES string
[F-].[K+]
InChI key
NROKBHXJSPEDAR-UHFFFAOYSA-M
extent of labeling
~5.5 mmol/g F- loading
Other Notes
Supported fluoride, useful as catalyst and supported base for elimination, addition and condensation reactions ; Potassium fluoride on aluminum oxide was shown by L. Weinstock et al. to be in reality KOH and K3AlF6 on aluminum oxide
Storage Class
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
wgk
nwg
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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L. Weinstock et al.
Tetrahedron Letters, 27, 3845-3845 (1986)
J.H. Clark et al.
Journal of the Chemical Society. Perkin Transactions 1, 2253-2253 (1983)
F. Texier-Boullet et al.
Tetrahedron, 41, 1259-1259 (1985)
Elena Chiurchiù et al.
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Highly functionalized furans are the key scaffolds of many pharmaceuticals and bioactive natural products. Herein, we disclose a new fruitful synthesis of polyfunctionalized furans starting from β-nitroenones and α-functionalized ketones. The protocol involves two steps promoted by solid supported species
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Carbonic anhydrase (CA; EC 4.2.1.1) was purified from the gill of the teleost fish Dicentrarchus labrax (European seabass). The purification procedure consisted of a single step affinity chromatography on Sepharose 4B-tyrosine-sulfanilamide. The enzyme was purified 84.9-fold with a yield of
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