60244
Potassium fluoride on aluminum oxide
extent of labeling: ~5.5 mmol/g F- loading
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About This Item
Linear Formula:
KF-Al2O3
Beilstein:
3902818
MDL number:
UNSPSC Code:
23151817
PubChem Substance ID:
NACRES:
NA.22
extent of labeling
~5.5 mmol/g F- loading
SMILES string
[F-].[K+]
InChI
1S/FH.K/h1H;/q;+1/p-1
InChI key
NROKBHXJSPEDAR-UHFFFAOYSA-M
Other Notes
Supported fluoride, useful as catalyst and supported base for elimination, addition and condensation reactions ; Potassium fluoride on aluminum oxide was shown by L. Weinstock et al. to be in reality KOH and K3AlF6 on aluminum oxide
Storage Class Code
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK
nwg
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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F. Texier-Boullet et al.
Tetrahedron, 41, 1259-1259 (1985)
L. Weinstock et al.
Tetrahedron Letters, 27, 3845-3845 (1986)
J.H. Clark et al.
Journal of the Chemical Society. Perkin Transactions 1, 2253-2253 (1983)
Elena Chiurchiù et al.
Molecules (Basel, Switzerland), 24(24) (2019-12-19)
Highly functionalized furans are the key scaffolds of many pharmaceuticals and bioactive natural products. Herein, we disclose a new fruitful synthesis of polyfunctionalized furans starting from β-nitroenones and α-functionalized ketones. The protocol involves two steps promoted by solid supported species
Deniz Ekinci et al.
Bioorganic & medicinal chemistry, 19(2), 744-748 (2011-01-08)
Carbonic anhydrase (CA; EC 4.2.1.1) was purified from the gill of the teleost fish Dicentrarchus labrax (European seabass). The purification procedure consisted of a single step affinity chromatography on Sepharose 4B-tyrosine-sulfanilamide. The enzyme was purified 84.9-fold with a yield of
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