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Merck
CN

60591

Potassium tetrakis(4-chlorophenyl)borate

Selectophore, ≥98.0%

Synonym(s):

Tetrakis(4-chlorophenyl)boron potassium

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About This Item

Linear Formula:
(ClC6H4)4BK
CAS Number:
Molecular Weight:
496.11
UNSPSC Code:
26111700
NACRES:
NB.61
PubChem Substance ID:
EC Number:
238-723-0
Beilstein/REAXYS Number:
4117827
MDL number:
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description

for ion-selective electrodes

Quality Segment

product line

Selectophore

assay

≥98.0% (AT), ≥98.0%

form

solid

SMILES string

[K+].Clc1ccc(cc1)[B-](c2ccc(Cl)cc2)(c3ccc(Cl)cc3)c4ccc(Cl)cc4

InChI

1S/C24H16BCl4.K/c26-21-9-1-17(2-10-21)25(18-3-11-22(27)12-4-18,19-5-13-23(28)14-6-19)20-7-15-24(29)16-8-20;/h1-16H;/q-1;+1

InChI key

SAGICZRAKJSWLD-UHFFFAOYSA-N

General description

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Application

Potassium tetrakis(4-chlorophenyl)borate was used as lipophilic anionic site in constructing fluorescent optode for sodium. It was also used as coating for the piezoelectric crystal in quantifying Potassium using quartz crystal microbalance.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Legal Information

Selectophore is a trademark of Merck KGaA, Darmstadt, Germany


pictograms

Skull and crossbones

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 3 Oral

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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R C Thomas et al.
Pflugers Archiv : European journal of physiology, 390(1), 96-98 (1981-04-01)
We have developed a filling solution for silanised microelectrodes consisting of potassium tetrakis (p-chlorophenyl) borate in octanol. Microelectrodes filled with this reference liquid ion-exchanger (RLIE) have equal selectivities to Na and K, and give the same membrane potential as do
Mark R Rheault et al.
The Journal of experimental biology, 207(Pt 12), 2173-2184 (2004-05-15)
Transport of the prototypical organic cation tetraethylammonium (TEA) by the Malpighian tubules, ureters and gut of Drosophila melanogaster was studied using two novel electrophysiological techniques. Both techniques exploited the high selectivity of the cation exchanger potassium tetra-p-chlorophenylborate for tetraalkylammonium compounds
Larisa Lvova et al.
Sensors (Basel, Switzerland), 21(4) (2021-03-07)
The metalloporphyrin ligand bearing incorporated anion-exchanger fragment, 5-[4-(3-trimethylammonium)propyloxyphenyl]-10,15,20-triphenylporphyrinate of Co(II) chloride, CoTPP-N, has been tested as anion-selective ionophore in PVC-based solvent polymeric membrane sensors. A plausible sensor working mechanism includes the axial coordination of the target anion on ionophore metal



Global Trade Item Number

SKUGTIN
60591-5G04061833354490
60591-100MG04061832676050
60591-1G04061832676067