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Potassium tetrakis(4-chlorophenyl)borate

Selectophore, ≥98.0%

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Synonym(s):
Tetrakis(4-chlorophenyl)boron potassium
Linear Formula:
(ClC6H4)4BK
CAS Number:
Molecular Weight:
496.11
Beilstein:
4117827
EC Number:
MDL number:
PubChem Substance ID:

grade

for ion-selective electrodes

Quality Level

product line

Selectophore

Assay

≥98.0% (AT)
≥98.0%

form

solid

SMILES string

[K+].Clc1ccc(cc1)[B-](c2ccc(Cl)cc2)(c3ccc(Cl)cc3)c4ccc(Cl)cc4

InChI

1S/C24H16BCl4.K/c26-21-9-1-17(2-10-21)25(18-3-11-22(27)12-4-18,19-5-13-23(28)14-6-19)20-7-15-24(29)16-8-20;/h1-16H;/q-1;+1

InChI key

SAGICZRAKJSWLD-UHFFFAOYSA-N

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General description

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Application

Potassium tetrakis(4-chlorophenyl)borate was used as lipophilic anionic site in constructing fluorescent optode for sodium. It was also used as coating for the piezoelectric crystal in quantifying Potassium using quartz crystal microbalance.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Legal Information

Selectophore is a trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Skull and crossbones

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Oral

Storage Class Code

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Larisa Lvova et al.
Sensors (Basel, Switzerland), 13(5), 5841-5856 (2013-05-09)
5,10,15,20-Tetraferrocenyl porphyrin, H2TFcP, a simple example of a donor-acceptor system, was tested as ligand for the development of a novel multi-transduction chemical sensors aimed at the determination of transition metal ions. The fluorescence energy transfer between ferrocene donor and porphyrin
Larisa Lvova et al.
Sensors (Basel, Switzerland), 21(4) (2021-03-07)
The metalloporphyrin ligand bearing incorporated anion-exchanger fragment, 5-[4-(3-trimethylammonium)propyloxyphenyl]-10,15,20-triphenylporphyrinate of Co(II) chloride, CoTPP-N, has been tested as anion-selective ionophore in PVC-based solvent polymeric membrane sensors. A plausible sensor working mechanism includes the axial coordination of the target anion on ionophore metal
R C Thomas et al.
Pflugers Archiv : European journal of physiology, 390(1), 96-98 (1981-04-01)
We have developed a filling solution for silanised microelectrodes consisting of potassium tetrakis (p-chlorophenyl) borate in octanol. Microelectrodes filled with this reference liquid ion-exchanger (RLIE) have equal selectivities to Na and K, and give the same membrane potential as do
Mark R Rheault et al.
The Journal of experimental biology, 207(Pt 12), 2173-2184 (2004-05-15)
Transport of the prototypical organic cation tetraethylammonium (TEA) by the Malpighian tubules, ureters and gut of Drosophila melanogaster was studied using two novel electrophysiological techniques. Both techniques exploited the high selectivity of the cation exchanger potassium tetra-p-chlorophenylborate for tetraalkylammonium compounds
Konrad Rudnicki et al.
Analytica chimica acta, 1085, 75-84 (2019-09-17)
In this paper, the electrochemical behavior of four fluoroquinolone antibiotics (FAs) [Ciprofloxacin (Cip), Enrofloxacin (Enr), Marbofloxacin (Mar) and Ofloxacin (Ofl)] at a polarized interface between two immiscible electrolyte solutions (ITIES) has been studied using ion-transfer voltammetry (ITV). The measurements were

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