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About This Item
Empirical Formula (Hill Notation):
C14H14O2P2S4
CAS Number:
Molecular Weight:
404.47
EC Number:
242-855-4
UNSPSC Code:
12352000
PubChem Substance ID:
Beilstein/REAXYS Number:
1024888
MDL number:
InChI key
CFHGBZLNZZVTAY-UHFFFAOYSA-N
InChI
1S/C14H14O2P2S4/c1-15-11-3-7-13(8-4-11)17(19)21-18(20,22-17)14-9-5-12(16-2)6-10-14/h3-10H,1-2H3
SMILES string
COc1ccc(cc1)P2(=S)SP(=S)(S2)c3ccc(OC)cc3
grade
purum
assay
≥98.0% (S)
mp
228-230 °C
Other Notes
The most efficient thiation reagent known till now, used for the thiation of carboxamides, ketones, lactones and imides, lactames, 3-oxocarboxylic derivatives (amides, esters and nitriles) and thio-S-esters; Selective thionation of oligopeptides; Reviews about LR
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I. Thomsen et al.
Organic Syntheses, 62, 158-158 (1984)
M.P. Cava et al.
Tetrahedron, 41, 5061-5061 (1985)
O.E. Jensen et al.
Tetrahedron, 41, 5595-5595 (1985)
R.A. Cherkasov et al.
Tetrahedron, 41, 2567-2567 (1985)
K. Clausen et al.
Journal of the Chemical Society. Perkin Transactions 1, 785-785 (1984)
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