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Merck
CN

62136

(+)-trans-Limonene 1,2-epoxide

analytical standard

Synonym(s):

(+)-trans-p-Mentha-1,8-diene 1,2-epoxide, (1S,2R,4R)-4-Isopropenyl-1-methyl-1-cyclohexene 1,2-epoxide, (1S,4R)-1,2-Epoxy-p-menth-8-ene

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About This Item

Empirical Formula (Hill Notation):
C10H16O
CAS Number:
6909-30-4
Molecular Weight:
152.23
UNSPSC Code:
85151701
NACRES:
NA.24
PubChem Substance ID:
329759712
MDL number:
MFCD16652609
Beilstein/REAXYS Number:
80940

Key Documents

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InChI

1S/C10H16O/c1-7(2)8-4-5-10(3)9(6-8)11-10/h8-9H,1,4-6H2,2-3H3/t8-,9-,10+/m1/s1

SMILES string

CC([C@@H]1CC[C@@]2(C)[C@@](O2)([H])C1)=C

InChI key

CCEFMUBVSUDRLG-BBBLOLIVSA-N

grade

analytical standard

assay

≥95.0% (sum of enantiomers, GC)

optical activity

[α]20/D +90±2°, neat

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

refractive index

n20/D 1.466

density

0.930 g/mL at 20 °C (lit.)

application(s)

food and beverages

format

neat

storage temp.

2-8°C

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

149.0 °F - closed cup

flash_point_c

65 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
BCCF7072
BCBZ5646
BCBS7505V
BCBT0145

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Q Q Hou et al.
Biochimica et biophysica acta, 1824(2), 263-268 (2011-09-20)
Limonene 1,2-epoxide hydrolase (LEH) is completely different from those of classic epoxide hydrolases (EHs) which catalyze the hydrolysis of epoxides to vicinal diols. A novel concerted general acid catalysis step involving the Asp101-Arg99-Asp132 triad is proposed to play an important
Stela Regina Ferrarini et al.
Veterinary parasitology, 157(1-2), 149-153 (2008-08-30)
Limonene, limonene oxide and eight beta-amino alcohol derivatives obtained by synthesis were investigated for the effect on egg hatchability and mortality rates of newly hatched larvae of the cattle tick Rhipicephalus (Boophilus) microplus. At the doses between 10 microg/ml and
Veslemøy Rolseth et al.
Toxicology, 170(1-2), 75-88 (2001-12-26)
Limonene has many commercial applications and has been introduced as an environmentally acceptable solvent replacing halogenated hydrocarbons. Occupational exposure to limonene presumably occurs simultaneously with other chemicals including oxidative agents and may exert a heavy strain on cellular detoxifying capacity
B N Chaudhuri et al.
Acta crystallographica. Section D, Biological crystallography, 55(Pt 4), 753-762 (1999-03-25)
Alpha 2u-globulin (A2U) is the major urinary protein excreted by adult male rats. The structure of a monoclinic crystal form of A2U was reported in 1992 [Böcskei et al. (1992). Nature (London), 360, 186-188]. The structures of an orthorhombic crystal
L D Lehman-McKeeman et al.
Toxicology and applied pharmacology, 112(2), 214-221 (1992-02-01)
It is well-established that binding of a chemical to alpha 2u-globulin is the rate-limiting step in the development of male rat-specific hyaline droplet nephropathy. Mice synthesize mouse urinary protein (MUP), a protein which is very similar to alpha 2u-globulin, but
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