69831
Molecular sieves, 3 Å
rod
Synonym(s):
Molecular Sieve UOP Type 3Å
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About This Item
Linear Formula:
KnNa12-n[(AlO2)12(SiO2)12] · xH2O
CAS Number:
UNSPSC Code:
23201100
MDL number:
form
rod
size
1/8 in.
pore size
3 Å pore diameter
General description
Molecular sieves are in the form of rods having pore diameter of 3Å. It participates in the synthesis of ecteinascidin 743 (a potential marine-derived antitumor agent) and vanillyl nonanoate (a model capsinoid compound).
Application
Molecular sieves may be employed in the enantioselective Friedel-Crafts alkylation of indoles with nitroalkenes. It may be employed for the drying of n-octane in a study.
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Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
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New efficient lipase from Yarrowia lipolytica for the resolution of 2-bromo-arylacetic acid esters.
Guieysse D, et al.
Tetrahedron Asymmetry, 15(22), 3539-3543 (2004)
Chiral phosphoric acid catalyzed enantioselective Friedel-Crafts alkylation of indoles with nitroalkenes: cooperative effect of 3 A molecular sieves.
Junji Itoh et al.
Angewandte Chemie (International ed. in English), 47(21), 4016-4018 (2008-04-18)
Enantioselective total synthesis of ecteinascidin 743.
Corey EJ, et al.
Journal of the American Chemical Society, 118(38), 9202-9203 (1996)