Skip to Content
Merck
CN

Key Documents

View All Documentation

69875

Molybdenumhexacarbonyl

technical

Synonym(s):

Hexacarbonylmolybdenum(0)

Sign In to View Organizational & Contract Pricing.

Select a Size

Change View

About This Item

Linear Formula:
Mo(CO)6
CAS Number:
13939-06-5
Molecular Weight:
264.00
NACRES:
NA.23
PubChem Substance ID:
329762021
UNSPSC Code:
12352103
EC Number:
237-713-3
MDL number:
MFCD00003466
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

vapor density

9.1 (vs air)

Quality Level

200

grade

technical

form

solid

reaction suitability

core: molybdenum, reagent type: catalyst

bp

156 °C (lit.)

mp

150 °C (dec.) (lit.)

density

1.96 g/mL at 25 °C (lit.)

SMILES string

[Mo].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/6CO.Mo/c6*1-2;

InChI key

KMKBZNSIJQWHJA-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

General description

Molybdenum hexacarbonyl is a colorless compound that sublimates and decomposes without melting at 150oC. It has an octahedral structure. Inherent sublimation of molybdenum hexacarbonyl permits it to perform as an active liquefaction catalyst. To form a catalyst it is adsorbed on dehydroxylated alumina forming subcarboyls.

Application

Alumina supported molybdenum hexacarbonyl acts as an active catalyst. It is used to synthesize MoO and MoC nanowires by electron beam induced deposition.

pictograms

Skull and crossbones
GHS06

signalword

Danger

hcodes

H331

Hazard Classifications

Acute Tox. 3 Inhalation

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
STBK4073
STBK3508
STBJ7128
STBJ5137
STBJ0101

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

An investigation of the chemistry of molybdenum hexacarbonyl on thin dehydroxylated alumina films in ultrahigh vacuum
Catalysis Letters, 91(1-2), 83-88 (2003)
Microstructural analysis and Transport Properties of MoO and MoC nanostructures prepared by focused electron beam-induced deposition
Makise K, et al
Scientific Reports, 4 (2014)
Patrik Nordeman et al.
The Journal of organic chemistry, 77(24), 11393-11398 (2012-12-05)
A bridged two-vial system aminocarbonylation protocol where Mo(CO)(6) functions as an external in situ solid source of CO has been developed. For the first time both nitro group containing aryl/heteroaryl iodides and bromides gave good to excellent yields in the
John Spencer
Future medicinal chemistry, 2(2), 161-168 (2011-03-24)
Microwave-mediated chemistry, involving the reduction of nitroarenes with molybdenum hexacarbonyl as a stoichiometric reducing agent, has been employed in the synthesis of a range of anilines. Many of these reactions exhibit high levels of chemoselectivity, tolerating unsaturation, steric hindrance and
Qingxi Meng et al.
Journal of molecular modeling, 18(8), 3489-3499 (2012-02-03)
Density functional theory (DFT) was used to investigate the Mo-catalyzed intramolecular Pauson-Khand reaction of 3-allyloxy-1-propynylphosphonates. All intermediates and transition states were optimized completely at the B3LYP/6-31 G(d,p) level [LANL2DZ(f) for Mo]. In the Mo-catalyzed intramolecular Pauson-Khand reaction, the C–C oxidative
View All Related Papers

Articles

Progress in Spintronic Materials

Spintronics offer breakthroughs over conventional memory/logic devices with lower power, leakage, saturation, and complexity.

Global Trade Item Number

SKUGTIN
69875-5G04061833358627
69875-25G04061832794471
69875-100G04061833381069

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service